The vapor pressures of CCl4 (A) and C₂HC 3 (B) between 7 = 350 and 360 K, can be determined empirically by the formulas In PA* 2790.78 = 9.2199 1 bar PB (T - 46.75) * 2345.4 In bar = 8.3922 (T - 80.45) where T is given in K, and the vapor pressures will be in units of bars. In this problem, assume that these two substances form an ideal solution in this temperature range, in all proportions. 2 (a) Find the mole fraction of CCl4 (component A) in both the liquid and vapor phases at T = 354 K, and an ambient pressure of 0.96 bar. (b) Suppose this mixture is heated slightly to a temperature of T = 358 K but its solution has the same composition (i.e. the same mole fractions of CCl4 and C2HCl3). What is the total vapor pressure of the solution now (in bars), and what is the mole fraction of CCl4 in the vapor?

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter12: Solutions
Section: Chapter Questions
Problem 12.83QE
icon
Related questions
Question
The vapor pressures of CCl4 (A) and C₂HCl3 (B) between T = 350 and 360 K, can be
determined empirically by the formulas
2790.78
(T - 46.75)
2345.4
(T- 80.45)
where T is given in K, and the vapor pressures will be in units of bars. In this problem,
assume that these two substances form an ideal solution in this temperature range, in all
proportions.
In
PA*
1 bar
In
PB*
1 bar
9.2199
= 8.3922
2
(a) Find the mole fraction of CCl4 (component A) in both the liquid and vapor phases at T =
354 K, and an ambient pressure of 0.96 bar.
(b) Suppose this mixture is heated slightly to a temperature of T = 358 K but its solution has
the same composition (i.e. the same mole fractions of CCl4 and C₂HCl3). What is the total
vapor pressure of the solution now (in bars), and what is the mole fraction of CCl4 in the
vapor?
Transcribed Image Text:The vapor pressures of CCl4 (A) and C₂HCl3 (B) between T = 350 and 360 K, can be determined empirically by the formulas 2790.78 (T - 46.75) 2345.4 (T- 80.45) where T is given in K, and the vapor pressures will be in units of bars. In this problem, assume that these two substances form an ideal solution in this temperature range, in all proportions. In PA* 1 bar In PB* 1 bar 9.2199 = 8.3922 2 (a) Find the mole fraction of CCl4 (component A) in both the liquid and vapor phases at T = 354 K, and an ambient pressure of 0.96 bar. (b) Suppose this mixture is heated slightly to a temperature of T = 358 K but its solution has the same composition (i.e. the same mole fractions of CCl4 and C₂HCl3). What is the total vapor pressure of the solution now (in bars), and what is the mole fraction of CCl4 in the vapor?
Expert Solution
steps

Step by step

Solved in 4 steps with 62 images

Blurred answer
Knowledge Booster
Phase Diagrams
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry: Principles and Practice
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
EBK A SMALL SCALE APPROACH TO ORGANIC L
EBK A SMALL SCALE APPROACH TO ORGANIC L
Chemistry
ISBN:
9781305446021
Author:
Lampman
Publisher:
CENGAGE LEARNING - CONSIGNMENT
Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781133611097
Author:
Steven S. Zumdahl
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning