The third law of thermodynamics relates the entropy (randomness) of matter to its absolute temperature. Which of the following statements are in agreement with the third law of thermodynamics? Realize, there may be more than one correct statement below!   1. In a gaseous state, the entropy of the system is zero   2. In a crystalline state, there is a tendency to minimize entropy   3. At absolute zero, the bond enthalpy in the crystal reaches a value of zero   4. At the melting point, the entropy of a system increases abruptly as the compound transforms into a liquid   5. At zero degrees kelvin, substances maximize entropy   6. As the temperature of a perfect crystal increases, the random vibrations of the molecules decrease

Explain each of the Laws of Thermodynamics and to which law would Entropy and Enthalpy apply. Thank you!

According to the second law of thermodynamics for any spontaneous process, the entropy of the universe (increases, decreases, or remains constant)

Consider the following reaction at constant pressure. Use the information here to determine the value of AS surr at 298 K. Predict whether or not this reaction will be spontaneous at this temperature. N₂(g) +202(g) → 2NO₂(g) AHrxn = +88.4 kJ mol-1 ASsurr = +88.4J K-1 mol-1, reaction is spontaneous Assurr = -88.4J K-1 mol-1, reaction is spontaneous ASsurr = -88.4J K-1 mol-1, reaction is not spontaneous ASsurr = +297 J K-1 mol-1, reaction is spontaneous ⒸASsurr = -297J K-1 mol-1, reaction is not spontaneous