Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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The reaction in this lab is an E1 reaction. Why won’t the reaction proceed via and E2
mechanism? In your answer consider what conditions are conducive to E2.

**Dehydration of Cyclohexanol to Cyclohexene**

**Reaction Overview:**
The image depicts the dehydration reaction of cyclohexanol to produce cyclohexene using phosphoric acid (H₃PO₄) as a catalyst.

**Reactants and Products:**

1. **Cyclohexanol (Reactant):**
   - Molecular Weight (MW): 100.16 g/mol
   - Boiling Point (bp): 160-161°C
   - Structure: A six-membered carbon ring with an -OH (hydroxyl) group attached.

2. **Cyclohexene (Product):**
   - Molecular Weight (MW): 82.14 g/mol
   - Boiling Point (bp): 83°C
   - Structure: A six-membered carbon ring with a double bond.
   - Note: Cyclohexene is distilled from the mixture after formation.

3. **Water (Product):**
   - Represented by the chemical formula H₂O, produced as a byproduct of the reaction.

**Reaction Mechanism:**
The dehydration of cyclohexanol involves the removal of a water molecule, primarily facilitated by the action of phosphoric acid, resulting in the formation of cyclohexene.

This reaction is crucial in organic synthesis, where it serves as a method for preparing alkenes from alcohols. The water formed is typically removed by distillation to drive the reaction to completion.
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Transcribed Image Text:**Dehydration of Cyclohexanol to Cyclohexene** **Reaction Overview:** The image depicts the dehydration reaction of cyclohexanol to produce cyclohexene using phosphoric acid (H₃PO₄) as a catalyst. **Reactants and Products:** 1. **Cyclohexanol (Reactant):** - Molecular Weight (MW): 100.16 g/mol - Boiling Point (bp): 160-161°C - Structure: A six-membered carbon ring with an -OH (hydroxyl) group attached. 2. **Cyclohexene (Product):** - Molecular Weight (MW): 82.14 g/mol - Boiling Point (bp): 83°C - Structure: A six-membered carbon ring with a double bond. - Note: Cyclohexene is distilled from the mixture after formation. 3. **Water (Product):** - Represented by the chemical formula H₂O, produced as a byproduct of the reaction. **Reaction Mechanism:** The dehydration of cyclohexanol involves the removal of a water molecule, primarily facilitated by the action of phosphoric acid, resulting in the formation of cyclohexene. This reaction is crucial in organic synthesis, where it serves as a method for preparing alkenes from alcohols. The water formed is typically removed by distillation to drive the reaction to completion.
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