
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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The normal boiling point of benzene is 80 °C. At 100 °C and 1 atm, which term is
greater in magnitude for the vaporization of benzene, ΔH or -TΔS?
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- The normal melting point of ethylene glycol, C₂H6O2, is -12.7 °C. For the process of melting, what is the sign of ArGº at: Temperature: 0.0 °C 25.0 °C 65.0 °C A,Gº: Submit + 0arrow_forwardAutomobiles and trucks pollute the air with NO. At 2000.0°C, Kc for the reaction is 7.42 × 10–4, and ΔH for the reaction is 180.6 kJ.N2(g)+O2(g)2NO(g) What is the value of Kc at 1000.0°C?arrow_forwardCalculate the normal boiling point of methanol CH₂OH in °C given the following data: AH VAP = 37.4 kJ/mol and AS VAP = 110.8 J/mol-K CH3OH (1)→ CH3OH (g)arrow_forward
- 3- Diethyl ether (CH3CH2OCH2CH3) was one of the first chemicals used as an anesthetic. At 34.6°C, diethyl ether has a vapor pressure of 760. torr, and at 17.9°C, it has a vapor pressure of 400 torr. What is the ΔH of vaporization for diethyl ether?arrow_forwardFor a certain reaction, ΔHº = −1.8 x 102 kJ mol−1 and the equilibrium constant at 800. K is 9.1 × 102 . Estimate the temperature at which the equilibrium constant is 1.0 × 106 .arrow_forwardFor an exothermic reaction ΔH < 0 ΔH > 0 ΔH = 0 H = 0arrow_forward
- Consider the synthesis of urea according to the equationCO2(g) + 2 NH3(g) −−→ (NH2)2CO(s) + H2O(l)Calculate the ∆rxnG−⊖−for the reaction at 25 ◦C for 3.25 mol of NH3 and an abundance of CO2. Assuming ∆rxnG−⊖− to be independent of temperature, what is the ∆Grxn for the reaction at a pressure of 10.0 atm? ∆rxnG−⊖−(CO2) = -394.36 kJ/mol ∆rxnG−⊖−(NH3)= -16.45 kJ/mol ∆rxnG−⊖−( (NH2)2CO)= -197.33 kJ/mol ∆rxnG−⊖−(H2O)= -273.13 kJ/molarrow_forwardOxygen (O₂) is necessary for cellular respiration; it must be transported from the lungs to tissues through the bloodstream. However, O₂ is not very soluble in water. The Keq of oxygen dissolving at 300.0 K is 7.64 x 10⁻⁴ and the Keq at 320.0 K is 5.23 x 10⁻⁴. Calculate the ∆H(dissolve) for oxygen solubility in water, in kJ/mol.arrow_forwardCalculate ΔGo for a reaction for which ΔHo = 24.6 kJ and ΔSo= 132 J/K at 298 K.arrow_forward
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