Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Question
The molar heat capacity of C2H4 (g) can be expressed by
?̅
?
(?)⁄? = 16.4105 −
6085.929 K
?
+
822826 K
2
?2
over the temperature range 300 K < T <
1000 K.
(i) Calculate S if one mole of ethene is heated from 300 K to 1000 K at constant volume.
(ii) Calculate S if one mole of ethene is heated from 300 K to 1000 K at constant pressure.
(iii) Show that the difference in results of above two processes is given by
∆?̅
? = ∆?̅
? + ? ln ?2
?1
(iv) Show above processes on a P-V diagram
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