Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- A 6.61g sample of an unknown salt (MM=116.82g//mol) is dissolved in 150.00g water in a coffee cup calorimeter. Before placing the sample in the water, the temperature of the salt and water is 23.72 C. After the salt has completely dissolved, the temperature of the solution is 28.54 C. Given that 156.61 g of solution increased in temperature by 4.82 °C, what quantity of heat, in J, was gained by the solution? Assume the specific heat of the solution is the same as water, 4.184 J/g• °C.arrow_forwardA 5.71 g sample of an unknown salt (MM = 116.82 g/mol) is dissolved in 150.00 g water in a coffee cup calorimeter. Before placing the sample in the water, the temperature of the salt and water is 23.72 °C. After the salt has completely dissolved, the temperature of the solution is 28.54 °C. What quantity of heat, in J, was gained by the solution? Assume the specific heat of the solution is the same as water, 4.184 J/g * C.arrow_forwardA student is asked to identify an unknown piece of metal. The metal has a mass of 12.34 g. It is placed in a boiling water bath and brought up to 99.98 oC. A coffee-cup calorimeter is set up with 103.25 mL of water (density = 1.00 g/mL and specific heat = 4.184 J/g.oC) at a room temperature of 21.30 oC. The metal is removed from the boiling water and placed in the calorimeter. A final temperature is recorded as 22.32 oC. Find the specific heatcapacity of the unknown metal. (Assume there is no heat loss)arrow_forward
- q represents the change in heat of a reaction or substance. The units of q are Joules (J) or kilojoules (kJ). For a well understood substance, we can calculate the specific heat which relates the mass of the substance in grams to the amount of heat in J required to raise that amount a certain temperature. We call that specific heat. The specific heat (Cs) of water is stated in the following way: C s ( H 2 O ) = 4.186 J g ∘ C This means that it takes 4.186 J of energy to raise the temperature of 1g of water by 1ºC. The relationship between q and Cs for a given substance is where m is mass (g) and ∆T is the change in temperature in ºC (final temp - initial temp). Calculate the heat change (q) in J when 4.297 grams of water is cooled from 3.967 ºC to -2.902 ºC. Enter your answer with one decimal place (tenths). Pay careful attention to the sign of your answer. The sign of ∆T is always the same as the sign for q.arrow_forwardWhen 6.54 grams of Zn is placed in 500.0 mL of 1.00 M CuSO4(aq) in a coffee cup calorimeter, it reacts completely to displace copper. The temperature of the solution rises from 20.0˚C to 30.4˚C. Assume the coffee cup itself gains no heat and that the solution has the same density (1.00 g/mL) and specific heat (4.184 J/g˚C) as pure water. (a) How much heat does the solution gain during this reaction? (in J)arrow_forward3. A 74.5 g piece of metal at 86.0°C is placed in 133 g of water at 21.0°C contained in a calorimeter. The metal and water come to the same temperature at 24.2°C. How much heat (in J) did the metal give up to the water? (Assume the specific heat of water is 4.18 J/g·°C across the temperature range.) J What is the specific heat (in J/g·°C) of the metal? J/g·°C 4. A 0.528 g sample of KCl is added to 51.7 g of water in a calorimeter. If the temperature decreases by 1.07°C, what is the approximate amount of heat (in J) involved in the dissolution of the KCl, assuming the heat capacity of the resulting solution is 4.18 J/g°C? J Is the reaction exothermic or endothermic? exothermicendothermic 5. When 2.56 g of methane burns in oxygen, 128 kJ of heat is produced. What is the enthalpy of combustion (in kJ) per mole of methane under these conditions? kJ/mol methane 6. Joseph Priestly prepared oxygen in 1774 by heating red mercury(II) oxide with sunlight focused through a lens. How much…arrow_forward
- A chemical reaction takes place inside a flask submerged in a water bath. The water bath contains 4.70 kg of water at 38.7 °C. During the reaction 55.6 kJ of heat flows out of the flask and into the bath. Calculate the new temperature of the water bath. You can assume the specific heat capacity of water under these conditions is -1 4.18 J∙g¯¹·K¯¹. Be sure your answer has the correct number of significant digits. 心。 °℃ x10 Sarrow_forwardn the laboratory a "coffee cup" calorimeter, or constant pressure calorimeter, is frequently used to determine the specific heat of a solid, or to measure the energy of a solution phase reaction.A student heats 63.03 grams of chromium to 98.03 °C and then drops it into a cup containing 79.71 grams of water at 23.19 °C. She measures the final temperature to be 28.85 °C.The heat capacity of the calorimeter (sometimes referred to as the calorimeter constant) was determined in a separate experiment to be 1.57 J/°C.Assuming that no heat is lost to the surroundings calculate the specific heat of chromium. Specific Heat (Cr) = ____________J/g °C.arrow_forwardA gas expands and does work on the surroundings equal to 4.92 Latm. At the same time, it releases 98.6 J of heat to the surroundings. What is the change in energy in J of the gas? (write the solution without decimals)arrow_forward
- A 4.81 g sample of an unknown salt (MM = 116.82 g/mol) is dissolved in 150.00 g water in a coffee cup calorimeter. Before placing the sample in the water, the temperature of the salt and water is 23.72°C. After the salt has completely dissolved, the temperature of the solution is 28.54°C. If 3.12 × 10³ J of heat was gained by the solution, what is the total heat for the dissolution reaction of the 4.81 g of salt? How many moles of the unknown salt were used in the reaction ? _______ J?arrow_forward1. A thermometer placed in a solution undergoing a chemical reaction indicates an increase in temperature as the reaction proceeds. Is this reaction endothermic or exothermic? Describe if heat energy is lost or gained from the reaction (the system) to the surroundings. What is the sign of the enthalpy change (AH) of this reaction? 2. A student performs a reaction and determines the enthalpy change (AH) to be 31.4 kJ. Will the temperature of the surrounding solution increase or decrease as a result of this chemical process? 3. If you hold 3 grams of ice in your hand at room temperature, your hand will become cold. a) Is the reaction H,O(s) – H,O(1) endothermic or exothermic? b) In which direction does heat flow?arrow_forwardWhen a 6.50 g sample of solid sodium hydroxide dissolves in 100.0 g of water in a coffee-cup calorimeter, the temperature of the water rises from 21.6 to 37.8oC. Was the chemical reaction (dissolving the solid) endothermic or exothermic? How do you know? Write a balanced chemical equation for this process. Determine how many joules of heat (q) were involved in changing the temperature of the water. If the heat that changed the temperature of the water was a result of the chemical reaction, determine the ΔH of the chemical reaction in kJ/mol of sodium hydroxide.arrow_forward
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