Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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3. A 74.5 g piece of metal at 86.0°C is placed in 133 g of water at 21.0°C contained in a calorimeter. The metal and water come to the same temperature at 24.2°C. How much heat (in J) did the metal give up to the water? (Assume the specific heat of water is 4.18 J/g·°C across the temperature range.)

 J
What is the specific heat (in J/g·°C) of the metal?
 J/g·°C
4. A 0.528 g sample of KCl is added to 51.7 g of water in a calorimeter. If the temperature decreases by 1.07°C, what is the approximate amount of heat (in J) involved in the dissolution of the KCl, assuming the heat capacity of the resulting solution is 4.18 J/g°C?
 J
Is the reaction exothermic or endothermic?
exothermicendothermic 
5. When 2.56 g of methane burns in oxygen, 128 kJ of heat is produced. What is the enthalpy of combustion (in kJ) per mole of methane under these conditions?
 kJ/mol methane
6. Joseph Priestly prepared oxygen in 1774 by heating red mercury(II) oxide with sunlight focused through a lens. How much heat (in kJ) is required to decompose 1.18 mol of red HgO(s) to Hg(l) and O2(g) under standard conditions? kJ
Calculate ΔH (in kJ) for the process Hg2Br2(s) → 2 Hg(l) + Br2(l) from the following information.
Hg(l) + Br2(l) → HgBr2(s)       
ΔH298
 = −170.7 kJ Hg(l) + HgBr2(s) → Hg2Br2(s
ΔH298
 = −36.2 kJ
 kJ
8. Using the Supplemental Data, calculate the standard enthalpy change (in kJ/mol) for each of the following reactions.
(a) 2 Cu(s) + Cl2(g) → 2 CuCl(s)
 kJ/mol
(b)  2 NaOH(s) + CO2(g) → Na2CO3(s) + H2O(g)
 kJ/mol
(c) Al2O3(s) + 3 H2(g) → 2 Al(s) + 3 H2O(l)
 kJ/mol
(d) Si(s) + 2 Cl2(g) → SiCl4(g)
 kJ/mol
9.The oxidation of the sugar glucose, C6H12O6, is described by the following equation.
C6H12O6(s) + 6 O2(g) → 6 CO2(g) + 6 H2O(l)      
ΔH = −2802.5 kJ/mol
The metabolism of glucose gives the same products, although the glucose reacts with oxygen in a series of steps in the body.
(a) How much heat in kilojoules can be produced by the metabolism of 13.1 g of glucose?
 kJ
(b) How many Calories can be produced by the metabolism of 13.1 g of glucose?
 Cal
10. Which bond in each of the following pairs of bonds is the strongest?
(a)  C–C or C≡C   C–CC≡C    
(b)  S–H or P–H   S–HP–H    
(c)
H–Br or H–F
H–BrH–F    
(d)
C–N or C=N
C–NC=N    
(e)
C–O or C≡O
C–OC≡O    
(f)
C–O or C–N
C–OC–N    
11. Using the bond enthalpies in the Average Bond Enthalpies table, determine the approximate enthalpy (in kJ) for each of the following reactions. (Assume the average bond enthalpy of the Cl–F bond is 254 kJ/mol.)
(a)  Cl2(g) + 3 F2(g) → 2 ClF3(g)
 kJ
(b)  H2C=CHCH3(g) + H2(g) → H3CCH2CH3(g)
 kJ
(c) 2 CH3(C=O)H(g) + 5 O2(g) → 4 CO2(g) + 4 H2O(g)
 kJ
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