Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- Answer 3.14 onlyarrow_forward4. The vapor pressures of CCI4 (A) and C2HCI3 (B) between T= 350 and 360 K, can be determined empirically by the formulas PA In 2790.78 = 9.2199- %3D 1 bar (T-46.75) PB In 1 bar 2345.4 3D8.3922- (T-80.45) where T is given in K, and the vapor pressures will be in units of bars. Assuming that these two substances form an ideal solution in this temperature range, in all proportions, find the mole fraction of CCI4 (component A) in both the liquid and vapor phases at T= 355 K, and an ambient pressure of 1.0 bar.arrow_forwardA ternary mixture of methane, ethane, and propane exist as gas. The temperature is 100 degree centigrade, and pressure is 35 bar. The gas composition is 0.21 (Methane), 0.43 (Ethane), and remainder for Propane. Methane (1) / Ethane (2)/ Propane(3) The accentric factor of the gases are (three decimal places) The critical compressibility of the gases are (three significant figures) The critical temperatures are (Kelvins) (one decimal place) The critical volumes (cubic centimeters per mol) are (one decimal place)arrow_forward
- (a)Using the compressibility chart, determine the compression factor (Z). Express your final answers in 3 significant figures (b)What would be the corresponding state of carbon dioxide? (Pc = 72.9 atm, Tc = 304.2 K) T (K) 200 P (atm) Tс (К) Pc (atm) Gas Argon 23.0 150.7 48.0 1.1 1.0 T- 2.00 0.9 I=1.50 0.8 Tx =1.30 0.7 to 0.6 T=1.20 0.5 T-1.10 0.4 Legend: X Methane O Ethylene A Ethane O Propane O n-Butane Iso-pentane • n-Heptane A Nitrogen T =1.00 0.3 Carbon dioxide Water 0.2 Average curve based on data on hydrocarbons 0.1 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 Reduced pressure P x of xarrow_forwardConsider cyclohexane at 175ºC. Determine Z and V (cm^3/mol) when P = 8.74 bar (saturated liquid)arrow_forwardPartial derivatives. Use Helmholtz a P =T² (1) %3D av ƏT T V and the ideal gas equation of state to show that the internal energy, U, of an ideal gas does not depend on the volume, V.arrow_forward
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