Table 3.2 provides the specific volume, isothermal compressibility, and volume expansivity of several liquids at 20°C and 1 bar25 for use in Problems 3.13 to 3.15, where ß and x may be assumed constant. Table 3.2: Volumetric Properties of Liquids at 20°C Isothermal Specific Volume Volume Molecular Compressibility K/10-5 bar! Expansivity B/10-3.°C-1 Formula Chemical Name VIL·kg- CH4O2 C6H;N CS2 Acetic Acid 0.951 9.08 1.08 Aniline 0.976 4.53 0.81 Carbon Disulfide 0.792 9.38 1.12 Chlorobenzene 0.904 7.45 0.94 C&H12 C4H100 C2H5OH Cyclohexane Diethyl Ether Ethanol Ethyl Acetate т-Хylene 1.285 1.401 11.3 18.65 1.15 1.65 1.265 11.19 1.40 C4H8O2 C3H10 CH;OH CCI4 C;H3 CHCI3 1.110 11.32 1.35 1.157 8.46 0.99 Methanol 1.262 12.14 1.49 Tetrachloromethane 0.628 10.5 1.14 Toluene 1.154 8.96 1.05 Trichloromethane 0.672 9.96 1.21 3.13. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is heated from 15°C to 25°C at a constant pres- sure of 1 bar. 3.14. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is compressed from 1 bar to 100 bar at a constant temperature of 20°C.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Answer 3.14 only

 

Table 3.2 provides the specific volume, isothermal compressibility, and volume expansivity
of several liquids at 20°C and 1 bar25 for use in Problems 3.13 to 3.15, where ß and x may be
assumed constant.
Table 3.2: Volumetric Properties of Liquids at 20°C
Specific
Volume
Isothermal
Volume
Molecular
V/L-kg-
Compressibility
K/10-5 bar!
Expansivity
B/10-3.°C-
Formula
Chemical Name
C2H4O2
C,H¬N
CS2
C6H5CI
C6H12
C4H100
C2HŞOH
C4H3O2
Acetic Acid
0.951
9.08
1.08
Aniline
0.976
4.53
0.81
Carbon Disulfide
0.792
9.38
1.12
Chlorobenzene
0.904
7.45
0.94
Cyclohexane
Diethyl Ether
Ethanol
1.285
11.3
1.15
1.401
18.65
1.65
11.19
11.32
1.265
1.40
Ethyl Acetate
т-Хylene
1.110
1.35
C3H10
CH3OH
CCI4
C;H8
CHCI3
1.157
8.46
0.99
Methanol
1.262
12.14
1.49
Tetrachloromethane
0.628
10.5
1.14
Toluene
1.154
8.96
1.05
Trichloromethane
0.672
9.96
1.21
3.13. For one of the substances in Table 3.2, compute the change in volume and work done
when one kilogram of the substance is heated from 15°C to 25°C at a constant pres-
sure of 1 bar.
3.14. For one of the substances in Table 3.2, compute the change in volume and work done
when one kilogram of the substance is compressed from 1 bar to 100 bar at a constant
temperature of 20°C.
Transcribed Image Text:Table 3.2 provides the specific volume, isothermal compressibility, and volume expansivity of several liquids at 20°C and 1 bar25 for use in Problems 3.13 to 3.15, where ß and x may be assumed constant. Table 3.2: Volumetric Properties of Liquids at 20°C Specific Volume Isothermal Volume Molecular V/L-kg- Compressibility K/10-5 bar! Expansivity B/10-3.°C- Formula Chemical Name C2H4O2 C,H¬N CS2 C6H5CI C6H12 C4H100 C2HŞOH C4H3O2 Acetic Acid 0.951 9.08 1.08 Aniline 0.976 4.53 0.81 Carbon Disulfide 0.792 9.38 1.12 Chlorobenzene 0.904 7.45 0.94 Cyclohexane Diethyl Ether Ethanol 1.285 11.3 1.15 1.401 18.65 1.65 11.19 11.32 1.265 1.40 Ethyl Acetate т-Хylene 1.110 1.35 C3H10 CH3OH CCI4 C;H8 CHCI3 1.157 8.46 0.99 Methanol 1.262 12.14 1.49 Tetrachloromethane 0.628 10.5 1.14 Toluene 1.154 8.96 1.05 Trichloromethane 0.672 9.96 1.21 3.13. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is heated from 15°C to 25°C at a constant pres- sure of 1 bar. 3.14. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is compressed from 1 bar to 100 bar at a constant temperature of 20°C.
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