The following two sets of reactions, ((a) and (b)), show possibilities for arrow pushing in individual reaction steps. Identify which is wrong and explain why. Next, using the correct arrow pushing, label which molecule is the nucleophile and which is the electrophile. (a) (b) H3C +1. C-CH3 Cl: H3C H3C-CI →:I–CH3 + :Cl: C-CI: H3C/ H3C H3C H,C-Cl: :I-CH3 + :CI: : I :* H3C C-CI: H3C/ H3C :Cl: C-CH3 > H3C H3C
The following two sets of reactions, ((a) and (b)), show possibilities for arrow pushing in individual reaction steps. Identify which is wrong and explain why. Next, using the correct arrow pushing, label which molecule is the nucleophile and which is the electrophile. (a) (b) H3C +1. C-CH3 Cl: H3C H3C-CI →:I–CH3 + :Cl: C-CI: H3C/ H3C H3C H,C-Cl: :I-CH3 + :CI: : I :* H3C C-CI: H3C/ H3C :Cl: C-CH3 > H3C H3C
Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions
Section19.SE: Something Extra
Problem 28VC
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