Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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10. А.
The following substitution reaction is monitored by measuring the optical rotation of the solution
as a function of time. Based on the results shown in the graph at the right determine whether the
reaction takes place by a SN1 or SN2 reaction pathway. Explain your reasoning.
+100
+50-
NaBr
CH(BrCHs
-50-
-100
Time
There are nine stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane. One of the stereoisomers
undergoes elimination so slowly compared to the other stereoisomers that there is effectively no E2
product formed. Draw the chair structure of this stereoisomer and explain why this is so.
В.
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Transcribed Image Text:10. А. The following substitution reaction is monitored by measuring the optical rotation of the solution as a function of time. Based on the results shown in the graph at the right determine whether the reaction takes place by a SN1 or SN2 reaction pathway. Explain your reasoning. +100 +50- NaBr CH(BrCHs -50- -100 Time There are nine stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane. One of the stereoisomers undergoes elimination so slowly compared to the other stereoisomers that there is effectively no E2 product formed. Draw the chair structure of this stereoisomer and explain why this is so. В.
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