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The following reduction potentials are known for various 3+ first-row transition metal ions in aqueous solution:   Mn3+(aq) + e- --> Mn2+(aq)            Eo = 1.51 V Fe3+(aq) + e- --> Fe2+(aq)     E0= 0.77 V Co3+(aq) + e- --> Co2+(aq)   E0= 1.84 V Explain why the reduction potential for Fe3+ is abnormally low.

The following reduction potentials are known for various 3+ first-row transition metal ions in aqueous solution:   Mn3+(aq) + e- --> Mn2+(aq)            Eo = 1.51 V Fe3+(aq) + e- --> Fe2+(aq)     E0= 0.77 V Co3+(aq) + e- --> Co2+(aq)   E0= 1.84 V Explain why the reduction potential for Fe3+ is abnormally low.

Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter17: Electrochemistry
Section: Chapter Questions
Problem 25P
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  1. The following reduction potentials are known for various 3+ first-row transition metal ions in aqueous solution:

 

Mn3+(aq) + e- --> Mn2+(aq)            Eo = 1.51 V

Fe3+(aq) + e- --> Fe2+(aq)     E0= 0.77 V

Co3+(aq) + e- --> Co2+(aq)   E0= 1.84 V

Explain why the reduction potential for Fe3+ is abnormally low.

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