The following initial rate data are for the reaction of mercury(II) chloride with oxalate ion: 2 HgCl, + C20,–2 Cr + Hg,Cl, + 2 Co, Experiment [HgCl],, M [C,0,?1o, M Initial Rate, M s- S.53x10-2 1.26x10-4 2.52x104 5.02x10-4 1.01x103 1 0.378 0.171 0.378 3 8.53x10-2 0.756 14 0.171 0.756 Complete the rate law for this reaction in the box below. Use the form k[A]"[B]" , where 'l' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. Rate = From these data, the rate constant is 2.

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The following initial rate data are for the reaction of mercury(II) chloride with oxalate ion:

\[ 2 \text{HgCl}_2 + \text{C}_2\text{O}_4^{2-} \rightarrow 2 \text{Cl}^- + \text{Hg}_2\text{Cl}_2 + 2 \text{CO}_2 \]

| Experiment | [HgCl₂]₀, M | [C₂O₄²⁻]₀, M | Initial Rate, M s⁻¹ |
|------------|-------------|---------------|----------------------|
| 1          | 8.53×10⁻²   | 0.378         | 1.26×10⁻⁴            |
| 2          | 0.171       | 0.378         | 2.52×10⁻⁴            |
| 3          | 8.53×10⁻²   | 0.756         | 5.02×10⁻⁴            |
| 4          | 0.171       | 0.756         | 1.01×10⁻³            |

Complete the rate law for this reaction in the box below.  
Use the form k[A]^m[B]^n, where '1' is understood for m or n and concentrations taken to the zero power do not appear.  
Don't enter 1 for m or n.

Rate = \_\_\_\_\_\_

From these data, the rate constant is \_\_\_\_\_\_ M⁻²s⁻¹.
Transcribed Image Text:The following initial rate data are for the reaction of mercury(II) chloride with oxalate ion: \[ 2 \text{HgCl}_2 + \text{C}_2\text{O}_4^{2-} \rightarrow 2 \text{Cl}^- + \text{Hg}_2\text{Cl}_2 + 2 \text{CO}_2 \] | Experiment | [HgCl₂]₀, M | [C₂O₄²⁻]₀, M | Initial Rate, M s⁻¹ | |------------|-------------|---------------|----------------------| | 1 | 8.53×10⁻² | 0.378 | 1.26×10⁻⁴ | | 2 | 0.171 | 0.378 | 2.52×10⁻⁴ | | 3 | 8.53×10⁻² | 0.756 | 5.02×10⁻⁴ | | 4 | 0.171 | 0.756 | 1.01×10⁻³ | Complete the rate law for this reaction in the box below. Use the form k[A]^m[B]^n, where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. Rate = \_\_\_\_\_\_ From these data, the rate constant is \_\_\_\_\_\_ M⁻²s⁻¹.
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