The equilibrium constant for the following reaction is 1.0 x 10²3. Cr³+ (aq) + H₂EDTA² (aq) ⇒ CrEDTA¯(aq) + 2H+ (aq) 0₂C-CH₂ CH2CO2 EDTA+ 0₂C-CH₂ N-CH₂-CH₂-N M CH₂ -CO₂ Ethylenediaminetetraacetate EDTA is used as a complexing agent in chemical analysis. Solutions of EDTA, usually containing the disodium salt Na₂H₂ EDTA, are used to treat heavy metal poisoning. Calculate [Cr³+] at equilibrium in a solution originally 0.0050 M in Cr³+ and 0.060 M in H₂ EDTA²- and buffered at pH = 6.00. Assume that H₂EDTA² form dominates at this pH. [Cr³+] = [

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
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Chapter17: Principles Of Chemical Reactivity: Other Aspects Of Aqueous Equilibria
Section17.6: Equilibria Involving Complex Ions
Problem 1.3ACP: Use the formation constant of [Au(CN)2] in Appendix K to determine the equilibrium concentration of...
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The equilibrium constant for the following reaction is 1.0 x 102³.
Cr³+ (aq) + H₂ EDTA² (aq) = CrEDTA¯(aq) + 2H+ (aq)
0₂C-CH₂-
CH2–CO2
CH2CO,
=
EDTA+
O₂C-CH₂
Ethylenediaminetetraacetate
EDTA is used as a complexing agent in chemical analysis. Solutions of EDTA, usually containing the disodium salt Na₂ H₂ EDTA, are used to treat
heavy metal poisoning. Calculate [Cr³+] at equilibrium in a solution originally 0.0050 M in Cr³+ and 0.060 M in H₂EDTA² and buffered at
3+
pH
6.00. Assume that H₂ EDTA² form dominates at this pH.
[Cr³+] =
N- -CH₂-CH₂-N
M
Transcribed Image Text:The equilibrium constant for the following reaction is 1.0 x 102³. Cr³+ (aq) + H₂ EDTA² (aq) = CrEDTA¯(aq) + 2H+ (aq) 0₂C-CH₂- CH2–CO2 CH2CO, = EDTA+ O₂C-CH₂ Ethylenediaminetetraacetate EDTA is used as a complexing agent in chemical analysis. Solutions of EDTA, usually containing the disodium salt Na₂ H₂ EDTA, are used to treat heavy metal poisoning. Calculate [Cr³+] at equilibrium in a solution originally 0.0050 M in Cr³+ and 0.060 M in H₂EDTA² and buffered at 3+ pH 6.00. Assume that H₂ EDTA² form dominates at this pH. [Cr³+] = N- -CH₂-CH₂-N M
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