Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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The effective rate constant for a gaseous reaction which has a Lindemann mechanism is 2.50 x 10-4 s-1 at 1.30 kPa and 2.10 x 10-5 s-1 at 12 Pa. Calculate the rate constant for the activation step in the mechanism.
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- The specific rate constant for the first-order decomposition of -1 N₂O5 (9) to NO2 (g) and O₂ (g) is 7.48 × 10-³ s¯ at a given temperature. Find the length of time required for the total pressure in a system containing N₂O5 at an initial pressure of 0.110 atm to rise to 0.150 atm . Express your answer using two significant figures. VE ΑΣΦ t = Submit Part B t = Submit Request Answer Find the length of time required for the total pressure in a system containing N₂O5 at an initial pressure of 0.110 atm to rise to 0.220 atm . Express your answer using two significant figures. ΨΕ ΑΣΦ Part C Request Answer ? Find the total pressure after 120 s of reaction. S Sarrow_forwardThe Arrhenius parameters for the gas-phase decomposit ion of cyclobutane, C4H8(g)→ 2 C2H4(g). are log(A/s-1) = 15.6 and Ea = 261 kJ mol- 1. What is the ha lf- life of cyclobutane at (a) 20 °C, (b) 500 °C?arrow_forwardGive a reaction rate for the provided mechanism and do not include the intermediates in the final equation. 1. For the spontaneous reaction in water: Re(HzO)z + 2 KCN →Re(CN)z2 + 2K*(aq) + 2 H2O The postulate mechanism is where all species are in aqueous phase k1 Re(H₂O)2 + CN- Re(H₂O)(CN) + H₂O equilibrium Re(H₂O)(CN) + CN-I2 Re(H₂O)(CN)2-² Re(H2O)(CN)2243 Re(CN)22 + H2O k2 slow fastarrow_forward
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