The deuterium kinetic isotope effect for the halogenation of an alkane is defined in the following equation, where X: = Cl•or Br. deuterium kinetic rate of homolytic cleavage of a C–H bond by X• rate of homolytic cleavage of a C–D bond by X. isotope effect Predict whether chlorination or bromination would have a greater deuterium kinetic isotope effect.
The deuterium kinetic isotope effect for the halogenation of an alkane is defined in the following equation, where X: = Cl•or Br. deuterium kinetic rate of homolytic cleavage of a C–H bond by X• rate of homolytic cleavage of a C–D bond by X. isotope effect Predict whether chlorination or bromination would have a greater deuterium kinetic isotope effect.
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter22: Organic Chemistry
Section: Chapter Questions
Problem 60QAP: Write an equation for the reaction of chloroacetic acid (Ka=1.5103) with trimethylamine (Kb=5.9105)...
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The deuterium kinetic isotope effect for the halogenation of an
Predict whether chlorination or bromination would have a greater deuterium kinetic isotope effect.
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