The above synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. In this synthesis, reagents from the table are used to carry out the indicated steps (shown in blue). In the box below, draw the structure of compound f.

Provide a retrosynthetic analysis and forward synthesis for the compound shown below. H- and any other reagent of one carbon or less.

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2. (a) Mark the alpha carbons with "a" and draw out the alpha hydrogens (if any are present). (b) If enolizable, draw a mechanism and the enolate product below. Use B: as a generic base. H₂N

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Kinetic control At low temperatures, molecules have low amounts of kinetic energy and therefore predominantly react through the pathway that has the lowest energy of activation and therefore proceeds at a faster rate. The product obtained through this pathway is referred to as the kinetic product. ▼ Part B Give the structure of compound A, the major product when the reaction is conducted at low temperatures. Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default. ► View Available Hint(s) Love + H-Br -55 °C A NN [1] A ⒸH: 120 EXP. CONT Marvin JS by ChemAxon SOZ O IL H N CI Br 1 P F

Design a synthesis for the compound shown. You may use any reagents and any organic compounds with less than four carbons and benzene as your starting materials. HO, O2N

draw by hand the complete mechanism for the saponification reaction of the given acetate when treated with sodium hydroxide in water, followed by an acid workup. include all relevant arrows and electrons and put a box around your final product.

Enamines can serve as enolate surrogates in reactions at the a-carbon. In the reaction sequence, the structures of the enamine addition product – the initial zwitterion and its neutral tautomer – are shown. Draw the structures of the two reactants forming these intermediates, and draw the structure of the final product, obtained via hydrolysis of the neutral intermediate. initial zwitterionic intermediate neutral intermediate tautomerization Reactants H,0 hydrolysis product Draw the two reactants. Draw the hydrolysis product. Select Draw Rings More Erase Select Draw Rings More Erase H H

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