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- Rank the following carbocations in order of increasing stability.7. Which substituent would be classified as a deactivating ortho/para director in an electrophilic aromatic substitution reaction? a) || -C-OH b) O || -O-C-CH3 c) -CI d) + -NH34) Draw the complete electron-pushing arrow mechanism for the following reductions. Explain, using resonance contributors, the regiochemistry that results in each case. ỌMe Na, MeOH ? NH3 CHO Na, MeOH ? NH3
- 5. Draw the major and minor products of the following reaction. (H3C),CCH,CH3 H2SO4 heat он5. Which bromocyclohexane starting material would react faster - the cis or trans, and explain why? Draw both chair forms of the starting material to prove your point. Br K* OC(CH) K* OC(CH); Br cis trans4) For the following reaction map, provide the products, or reagents/ direction of the reaction arrow! MeO OMe MeO OH
- What must be done to OH´ to make it a good leaving group? The transition (to the right) is brought about by heating the starting material with a) Mg and anh. Ether b) KOH in alcohol H2O d) H3PO4 OH The alkene which is the most stable is ... a) CH3CH2 b) с) CH3CH2 CH3 CH3 CH3 H H H H CH3 CH3 H d) e) f) They are equal in CH;CH,CH2 c=c CH3 CH;CH2 c=c CH3 H H stability H HDraw the alkene that would react with the reagent given to account for the product formed. ? + H₂O H₂SO4 CH3 CH3 CHCCH3 OH CH3 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. Sn [F ChemDoodleDetermine the mechanism of nucleophilic substitution of each reaction and draw the products, including stereochemistr CH₂CH3 CI Br + CN d. + CH3COOH a. acetone + -OCH3 e. DMF f. b. C. ||||| a ||||| Br H Br CH2CH2CH3 + CH3OH DMSO H CH3 CI Br + OCH₂CH3 + CH3CH₂OH
- Draw the major organic product(s) of the following reaction. 1 eq. NANH2, NH3(0) CH;CH,CH,CH,-Br H-CEC-H • You do not have to consider stereochemistry. • Separate multiple products using the + sign from the drop-down menu. • If no reaction occurs, draw the organic starting material. P. opy aste ノ/ ChemDoodle >Draw the starting structure that would lead to this major product under these conditions. -> Select to Draw HBr (1 equiv) H2O2 BrDraw the major product of this reaction. Include stereochemistry if applicable. Ignore byproducts. CI CH³ONa heat : Br A