Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Table 1. Vapor Pressure of Water at Different Temperatures
Temperature, C
PH,0, mm Hg
Temperature, °C
PHo, mm Hg
16°C
13.6
22 °C
19.8
17 °C
14.5
23 °C
21.1
18 °C
15.5
24 °C
22.4
19 °C
16.5
25 °C
23.8
20 °C
17.5
26 °C
25.2
21 °C
18.7
27 °C
26.7
A reaction of 0.028 g of magnesium with excess hydrochloric acid generated 31.0 mL of hydrogen
gas. The gas was collected by water displacement in a 22 °C water bath. The barometric pressure
in the lab that day was 746 mm Hg.
1. Use Dalton's law and the vapor pressure of water at 22 °C (Table 1) to calculate the partial
pressure of hydrogen gas in the gas collecting tube.
2. Use the combined gas law to calculate the "corrected" volume of hydrogen at STP. Hint:
Watch your units for temperature and pressure!
3. What is the theoretical number of moles of hydrogen that can be produced from 0.028 g of
Mg? Hint: Refer to Equation 1 for the balanced equation for the reaction.
4. Divide the corrected volume of hydrogen by the theoretical number of moles of hydrogen to
calculate the molar volume (in L/mol) of hydrogen at STP.
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Transcribed Image Text:Table 1. Vapor Pressure of Water at Different Temperatures Temperature, C PH,0, mm Hg Temperature, °C PHo, mm Hg 16°C 13.6 22 °C 19.8 17 °C 14.5 23 °C 21.1 18 °C 15.5 24 °C 22.4 19 °C 16.5 25 °C 23.8 20 °C 17.5 26 °C 25.2 21 °C 18.7 27 °C 26.7 A reaction of 0.028 g of magnesium with excess hydrochloric acid generated 31.0 mL of hydrogen gas. The gas was collected by water displacement in a 22 °C water bath. The barometric pressure in the lab that day was 746 mm Hg. 1. Use Dalton's law and the vapor pressure of water at 22 °C (Table 1) to calculate the partial pressure of hydrogen gas in the gas collecting tube. 2. Use the combined gas law to calculate the "corrected" volume of hydrogen at STP. Hint: Watch your units for temperature and pressure! 3. What is the theoretical number of moles of hydrogen that can be produced from 0.028 g of Mg? Hint: Refer to Equation 1 for the balanced equation for the reaction. 4. Divide the corrected volume of hydrogen by the theoretical number of moles of hydrogen to calculate the molar volume (in L/mol) of hydrogen at STP.
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