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Solved in 3 steps with 1 images
- Which nucleophile would prefer simple addition over conjugate addition? CH3MgBr NaCN CH3CH2NH2 (CH3CH2)2CuLiDraw the major organic product(s) of the following reaction. 1 eq. NANH2, NH3(0) CH;CH,CH,CH,-Br H-CEC-H • You do not have to consider stereochemistry. • Separate multiple products using the + sign from the drop-down menu. • If no reaction occurs, draw the organic starting material. P. opy aste ノ/ ChemDoodle >6). What do you think would be the better nucleophile? Cu Organocopper reagent Cu Organocuprate reagent
- C) 30. In the presence of a nucleophile, which of the following will undergo conjugate addition? OCH3 HEVL OCH3True or false 1.an intermediate is produced in the SN2 reactiom is a carboncation. 2.In SN1 reactions nucleophile HI will react faster than HCL 3.Halogenated waste can be disposed off in a general waste solvent.Question 10: Identify which reagents you would use to achieve the following transformations. a. b. C. CI OH OH OH 55... SH OTS CN Br
- 149) Why is a tertiary alcohol more reactive with hydrogen halides, than secondary alcohols? Because secondary alcohols are smaller and therefore less reactive for the attack of halide nucleophile. Because tertiary alcohols have more hydrogen atoms available for substitution reactions. Because a tertiary alcohol can form a more stable carbocation as an intermediate in the reaction. Only the 1st and the 2nd statements are acceptable.Arrange the compounds below in order of increasing reactivity in a SN2 reaction. 1. (CH3)2СНCI 2. CH3CH2B1 3. CH3CH2C1 A) 1; 2; 3 В) 3;B 2; 1 C) 1; 3; 2 D) 2; 1; 3 E) 3; 1; 2From each pair, select the stronger nucleophile. Q.) CH3OCH3 or CH3SCH3
- 2. Complete the table below indicating what is important in each category for an E1 or E2 reaction. E1 Rate Law Best Solvent Alkene geometry outcome How does electrophile substitution affection the reaction? Does leaving group ability affect the rate? Does base strength affect the rate? Does/how does base type affect product structure? E21. Rank the following nucleophiles in order from slowest S,2 reaction rate to fastest if DMSO is the solvent. PH SH A B EIdentify the best conditions to complete the SN2 reaction shown below. A) CH3I, THF B) CH3CH₂I, THE C) CH3CH₂CCNa, THF D) CH3CH₂CCNA, CH3OH E) KI, THF