Student A prepared a concentration cell (L) where the cathode half-cell uses an equilibrium solution of [PbBr4]²- as the source of bromide ions. On the other hand, Student B prepared a galvanic cell (H), where the bromide ion concentration in the anode is equal to that in the cathode of cell L. Cell L Pt(s) | Br2) | Br (39) (1.0 M) || Br-(ag) (x M) from [PbBr4] (ag) Br2(1) | Pt(s) Cell H Pt(s) | Br21) | Br (ag) (x M) || BrO3 (ag) (0.43 M), H(aq) (1.00 M) | Br2) | Pt(s) Given: Ereduction Br2)/Br-(ag) = 1.07 V

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Student A prepared a concentration cell (L) where the cathode half-cell uses an equilibrium solution of [PbBr4]²- as
the source of bromide ions. On the other hand, Student B prepared a galvanic cell (H), where the bromide ion
concentration in the anode is equal to that in the cathode of cell L.
Cell L
Pt(s) | Br21) | Br (ag) (1.0 M) || Br-(ag) (x M) from [PbBr4] (ag) Br2(1) | Pt(s)
Cell H
Pt(s) | Br21) | Br(ag) (x M) || BrO3(aq) (0.43 M), H*(ag) (1.00 M) | Br2) | Pt(s)
Given: Ereduction Br2(/Br-(ag) = 1.07 V
Transcribed Image Text:Student A prepared a concentration cell (L) where the cathode half-cell uses an equilibrium solution of [PbBr4]²- as the source of bromide ions. On the other hand, Student B prepared a galvanic cell (H), where the bromide ion concentration in the anode is equal to that in the cathode of cell L. Cell L Pt(s) | Br21) | Br (ag) (1.0 M) || Br-(ag) (x M) from [PbBr4] (ag) Br2(1) | Pt(s) Cell H Pt(s) | Br21) | Br(ag) (x M) || BrO3(aq) (0.43 M), H*(ag) (1.00 M) | Br2) | Pt(s) Given: Ereduction Br2(/Br-(ag) = 1.07 V
c) Write the overall redox reaction for the electrochemical cell H.
d) Given that the electrochemical cell H gives a potential of 0.350 V, determine the standard potential for
the reduction of BrO3 (ag) to Br2(1).
Transcribed Image Text:c) Write the overall redox reaction for the electrochemical cell H. d) Given that the electrochemical cell H gives a potential of 0.350 V, determine the standard potential for the reduction of BrO3 (ag) to Br2(1).
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