Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Starting with [CV] = 1.0x105 M and [NaOH]; = 0.050 M, a set of their reaction kinetics data was collected over 3
minutes and plotted as shown below,
In[CV+]
-11.4
-11.6
-11.8
-12
-12.2
-12.4
-12.6
-12.8
0
20
40
Crystal Violet Kinetics First Order
60
80
100
time (sec)
k =
120
140
160
y = -0.0059x - 11.587
R² = 0.9987
180
The line fit data are represented by the first-order integrated rate law: [CV] = [CV]oekt
Use the values obtained by the line fit of [CV*]o and k from for all the following calculations. Write these
parameters below, rounded to 2 significant figures with units!
[CV] =
200
Is the concentration of crystal violet at the time of mixing identical to the initial concentration calculated
from the graph (at the beginning of data collection)? Why?
Calculate the instantaneous rate of crystal violet consumption at the beginning of the data collection, t = 0
seconds.
Rateo k[CV]o =
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Transcribed Image Text:Starting with [CV] = 1.0x105 M and [NaOH]; = 0.050 M, a set of their reaction kinetics data was collected over 3 minutes and plotted as shown below, In[CV+] -11.4 -11.6 -11.8 -12 -12.2 -12.4 -12.6 -12.8 0 20 40 Crystal Violet Kinetics First Order 60 80 100 time (sec) k = 120 140 160 y = -0.0059x - 11.587 R² = 0.9987 180 The line fit data are represented by the first-order integrated rate law: [CV] = [CV]oekt Use the values obtained by the line fit of [CV*]o and k from for all the following calculations. Write these parameters below, rounded to 2 significant figures with units! [CV] = 200 Is the concentration of crystal violet at the time of mixing identical to the initial concentration calculated from the graph (at the beginning of data collection)? Why? Calculate the instantaneous rate of crystal violet consumption at the beginning of the data collection, t = 0 seconds. Rateo k[CV]o =
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