reaction steps. A carbon tetrachloride production process consists of a reactor and a separator sys Agas stream containing 90 mole % chlorine and the balance methane is fed to the reactor. In the reactor a single-pass methane conversion of essentially 100% is attair the mole ratio of carbon tetrachloride to chloroform in the reactor product is 4:1, and negligible amounts of methyl chloride and methylene chloride are formed. The produca stream flows to a

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
icon
Related questions
Question
chlorination to form methylene chloride (CH₂Cl₂), chloroform (CHCl3), and carbon
tetrachloride (CC14) in different reaction steps.
A carbon tetrachloride production process consists of a reactor and a separator system.
gas
gas stream containing 90 mole % chlorine and the balance methane is fed to the
deactor. In the reactor a single-pass methane conversion of essentially 100% is attained,
the mole ratio of carbon tetrachloride to chloroform in the reactor product is 4:1, and
negligible amounts of methyl chloride and methylene chloride are formed. The product
stream flows to a separator, from which two streams emerge: a liquid, which contains
essentially all of the carbon tetrachloride and chloroform in the reactor effluent, and the
gas containing the chlorine and hydrogen chloride.
(a)
(b)
(c)
Write the chemical equations of the four reactions of methane chlorination and
give the two main overall reactions ignoring the ones producing negligible
amounts.
Explain the reason for the chlorine presence in the reactor outlet stream.
Using a basis of 100 kmol.h¹ combined feed to the reactor, calculate the molar
flow rate and molar composition of the reactor outlet.
14
Transcribed Image Text:chlorination to form methylene chloride (CH₂Cl₂), chloroform (CHCl3), and carbon tetrachloride (CC14) in different reaction steps. A carbon tetrachloride production process consists of a reactor and a separator system. gas gas stream containing 90 mole % chlorine and the balance methane is fed to the deactor. In the reactor a single-pass methane conversion of essentially 100% is attained, the mole ratio of carbon tetrachloride to chloroform in the reactor product is 4:1, and negligible amounts of methyl chloride and methylene chloride are formed. The product stream flows to a separator, from which two streams emerge: a liquid, which contains essentially all of the carbon tetrachloride and chloroform in the reactor effluent, and the gas containing the chlorine and hydrogen chloride. (a) (b) (c) Write the chemical equations of the four reactions of methane chlorination and give the two main overall reactions ignoring the ones producing negligible amounts. Explain the reason for the chlorine presence in the reactor outlet stream. Using a basis of 100 kmol.h¹ combined feed to the reactor, calculate the molar flow rate and molar composition of the reactor outlet. 14
Problem 3
Methane reacts with chlorine (atomic weight 35.5) to produce methyl chloride (CH3CI)
and hydrogen chloride (HCI). Once formed, the methyl chloride may undergo further
chlorination to form methylene chloride (CH₂C₂), chloroform (CHCb), and carbon
tetrachloride (CCl4) in different reaction steps.
A carbon tetrachloride production process consists of a reactor and a separator system.
A gas stream containing 90 mole % chlorine and the balance methane is fed to the
reactor. In the reactor a single-pass methane conversion of essentially 100% is attained,
the mole ratio of carbon tetrachloride to chloroform in the reactor product is 4:1, and
negligible amounts of methyl chloride and methylene chloride are formed. The product
stream flows to a separator, from which two streams emerge: a liquid, which contains
essentially all of the carbon tetrachloride and chloroform in the reactor effluent, and the
gas containing the chlorine and hydrogen chloride.
the four reactions of mathana chlorination and
14
Transcribed Image Text:Problem 3 Methane reacts with chlorine (atomic weight 35.5) to produce methyl chloride (CH3CI) and hydrogen chloride (HCI). Once formed, the methyl chloride may undergo further chlorination to form methylene chloride (CH₂C₂), chloroform (CHCb), and carbon tetrachloride (CCl4) in different reaction steps. A carbon tetrachloride production process consists of a reactor and a separator system. A gas stream containing 90 mole % chlorine and the balance methane is fed to the reactor. In the reactor a single-pass methane conversion of essentially 100% is attained, the mole ratio of carbon tetrachloride to chloroform in the reactor product is 4:1, and negligible amounts of methyl chloride and methylene chloride are formed. The product stream flows to a separator, from which two streams emerge: a liquid, which contains essentially all of the carbon tetrachloride and chloroform in the reactor effluent, and the gas containing the chlorine and hydrogen chloride. the four reactions of mathana chlorination and 14
Expert Solution
steps

Step by step

Solved in 4 steps with 10 images

Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The