R Ph3P CI Ph₂P CI H₂ Rh Rh PPh3 A *** «Η PPh3 PPh3 Me F PPh3 PPh3 Ph₂P CI II E H Rh PPh3 B H Ph₂P, Rh CI R H H PPh3 PPh3 Me Ph3P.. CI Ph₂P, D CI R PPh3 H Rh: Rh H PPh3 R H PPh3

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter5: Thermochemistry
Section: Chapter Questions
Problem 5.104QE
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Question

Given the following catalytic cycle. 

Label each reaction using the following process:

a. oxidative addition
b. reductive elimination
c. ligand subsitution
d. alkyl migration
e. hydride shift
f. β-hydrogen elimination

Identify the type of organometallic reaction at each step
From:
1. A to B
2. B to C
3. C to D
4. D to E

R
Ph3P
CI
Ph₂P
CI
H₂
Rh
Rh
PPh3
A
***
«Η
PPh3
PPh3
Me
F
PPh3
PPh3
Ph₂P
CI
II
E
Ph₂P,
CI
R
H
Rh
PPh3
B
H
H
Rh
H
PPh3
PPh3
Me
Ph₂P,
D CI
PPh3
Ph3P.. H
Ph₂P
CI
R
H
Rh:
Rh
PPh3
R
H
PPh3
Transcribed Image Text:R Ph3P CI Ph₂P CI H₂ Rh Rh PPh3 A *** «Η PPh3 PPh3 Me F PPh3 PPh3 Ph₂P CI II E Ph₂P, CI R H Rh PPh3 B H H Rh H PPh3 PPh3 Me Ph₂P, D CI PPh3 Ph3P.. H Ph₂P CI R H Rh: Rh PPh3 R H PPh3
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