Question 5. Draw the following complexes in skeletal form. (note: the "μ "before one of the chlorides in the Al-complex indicates that this chloride is engaged in a different type of bonding mode than the other chlorides. Also, be sure to consider the significance of use of brackets "[]" in this complex. For the Cr - complex 6 be sure to consider the implications of the ŋ descriptor before the benzene ligand and the significance this has on the ligand's binding mode): [4 pts 6 ] [AIC₁₂ (µ - CI)]₂, (n° - C¸H¸) Cr(CO)¸ 2 6 6
Q: 2) Part of the 'H NMR spectrum for a dipeptide recorded in D₂O is shown below. The signal for the CH…
A: When molecules are placed in a strong magnetic field, the nuclei of some atoms will begin to behave…
Q: The energy (or more correctly, the wavenumbers) for an allowed rotational transition of a linear…
A: Step 1: Step 2: Step 3: Step 4:
Q: For the reaction 2CO (g) ⇌ 2CO (g) + O (g), K = 6.4 x 10-7. If 1.0 x 10-3 moles of CO2 is placed in…
A:
Q: You may draw the structures in either Kekule, condensed, or mixed format initially. In the tables…
A: The objective of this question is to interpret spectra to estimate molecular structures by…
Q: in a sample of 47,500 silver atoms it was discovered that 35.8% of them had a mass of 107.35 amu and…
A: The objective of the question is to calculate the number of silver atoms
Q: If the following polysaccharide were to attach to a protein, to which atom(s) in the carbohydrate…
A: These are the neutral carbohydrates which consist of several monosaccharide units of glycans or…
Q: What is the major organic product obtained from the following reaction? Он H3CO-S о-осно о NaOH,…
A: The main objective of this reaction is to find out the major product of phenol after reacting with…
Q: 2. Draw structures of the polymers you would expect to obtain from the following reactions: Et₂N a.…
A: Polyethers: When alkyl dihalides are treated with diols in presence of base, they form…
Q: Identify the principal conjugate acid/base pair and calculate the ratio between them in a solution…
A: Sulfurous acid (H2SO3) is a diprotic acid.The dissociation reaction for H2SO4 is as follows: H2SO3…
Q: Write the systematic name of each organic molecule: structure CH3 O CH3-CH-CH-C-CH2-OH OH name ☐…
A: Given that, the structure of the organic molecules is as follows:
Q: Part A MISSED THIS? Watch IWE: Calculating AHxn from Bond Energies; Read Section 10.10. You can…
A: Given,The combustion reaction is:
Q: Which would be the major isolated organic product of the reaction shown? B) E) a different product…
A: Organic reactions can be defined as the reactions in which organic reactants react with each other…
Q: 9. [-/0.1 Points] DETAILS MY NOTES 0/4 Submissions A mixture of 0.1027 mol of H2O, 0.1254 mol of…
A: For the gas-phased reaction:H2O(g) + CH4(g) ⇌ CO(g) + 3H2(g)It is required to determine the…
Q: Organic compound H₁C-C=C-CH3 H₂C OH -(CH2)-CH3 Cl Cl Functional group
A: 1) alkyne (carbon carbon triple bond) is the functional group in 2-butyne. 2) carboxylic acid (-COOH…
Q: What is the major product
A: Step 1:Step 2: Step 3: Step 4:
Q: 4-Give the IUPAC name for each compound
A: Step 1:- Steps followed while naming are :- 1.) 4-Ethyloctane 1. Select the longest continuous…
Q: Please correct answer and don't use hend raiting
A: Atom I: This is a carbon atom double-bonded to an oxygen (ketone group), with two additional single…
Q: - Predict the product of the following reactions. Part A OEt Ph 1. NaOEt, EtOH, heat 2. H₂O+ quench…
A: We have to predict the products.
Q: Draw structures for the carbonyl electrophile and enolate nucleophile that react to give the aldol…
A: Aldol condensation is a condensation reaction in which an enol or an enolate ion reacts with a…
Q: 322 II. Calculations Show all of your work, where indicated, including any formulas, units, etc. Pay…
A: Given : Reaction of permanganate ion and Fe (II).Permanganate ion : MnO4- Iron (II) : Fe2+Oxidation…
Q: What is the name of the MAJOR product of this reaction? CH3 H3C OH H₂SO, heat H3C
A: Given,The reaction:
Q: dont provide handwritiing solution ...
A: The objective of the question is to identify the correct reagent that can transform a primary…
Q: Determine the amount of time (in hours) that a 16.8 ampere current must be applied to a 2.0…
A: The objective of the question is to find out the time required to produce a certain amount of Zinc…
Q: 3. Predict the products of the following irreversible additions to carboxylic acids. OH excess…
A: Reaction 1: This reaction produces the carboxylate form of the acid. This is because carboxylic…
Q: Consider the mechanism for the given nucleophilic substitution reaction. Part:0/5 Part 1 of 5 と…
A: The nucleophilic substitution product is 2-ethoxy-2-methylbutane .Explanation:
Q: The ache, or "burn", you feel in your muscles during strenuous exercise is caused by the…
A: Method 1: Step-by-step procedure to calculate the concentration of the sample of lactic acid: Step…
Q: a. How many orbitals in an atom can have the designation 3d2? b. How many orbitals in an atom can…
A: An atomic orbital is a space in which the chance of an electron occurring is at its highest level. A…
Q: Predict the product of this organic reaction: NH2 HO C-CH2-CH3 + CH3 CH CH3 P + H2O Specifically, in…
A:
Q: Which of the following is not a reasonable retrosynthesis? OH Br OMe OTS
A: The term "retrosynthesis" comes from combining "retro," meaning backwards, with "synthesis,"…
Q: 5. Sup step-by-step mech eh 802&t Nah cores + p-ph 0 1 ту Es Ph
A: The objective of the question is to find out the step by step mechanism for the given reaction.In…
Q: Longifolene is a terpene which has the structure A. a) Identify which class of terpenes it belongs…
A: Terpenes belong to the biggest class of secondary metabolites and consist of five carbon isoprene…
Q: Matching-Write the letter next to the correct structure. (A) N,N-dimethyl-2-butanamine (B)…
A: The objective of this question is to write the correct names for the given structures.Given all…
Q: Convert product C, shown below, into its Fischer projection. One of the carbon atoms has been marked…
A: The objective of the question is to find the position number from of atoms in the given fischer…
Q: Type of reaction K3P04, CuS04 Molecular equation Total ionic equation Net ionic equation
A: The balanced molecular equation is:3CuSO4(aq)+2K3PO4(aq)→Cu3(PO4)2(s)+3K2SO4(aq)Total ionic…
Q: Br2 (low conc.) Br н Br
A: The objective of the question is to find out the major product of the given reaction. In the…
Q: Calculate the volume in milliliters of a 1.05 mol/L sodium chloride solution that contains 50.0 mmol…
A: Step 1: Converting the 'mmoles' of NaCl to 'moles' of NaCl:According to the question,We need to…
Q: if the original two test tubes are not completely emptied and there is some salt left in both test…
A: The original two test tubes are not completely emptied and there is some salt left in both test…
Q: (b) The 1H-NMR spectrum of compound B, C5 H10O2, consists of the following signals: 81.2 (d, 6H),…
A: NMR spectroscopy is a very important tool for the determination of the structure of the organic…
Q: Draw all of the products that result after complete hydrolysis of the following mol N H3O+
A: The chemical reaction in which water molecule break a polar bond by acting as a nucleophile in a…
Q: Tube Tris/CaCl, pH8 (ml) BAPNA Trypsin (µL) (µL) Final [BAPNA] (mM) 1 2.895 5.0 100 2 2.89 10.0 100…
A: For BAPNA (Conversions) 5 uL x 1000uL1mL = 0.005 mL BAPNA10 uL x 1000uL1mL = 0.010 mL BAPNA25 uL x…
Q: A gas in an open container is heated from 27°C to 127°C. The fraction of the original amount of the…
A: Initial temperautre ,T1 = 27°C = (273+27)K = 300KFinal temperature, T2 = 127°C =(273+127)K = 400KWe…
Q: A disaccharide consists of the molecules of D-glucose and D-glucosamine joined by (1a,…
A: The objective of this question is to represent molecular structures accurately and predict the…
Q: Provide the major organic product of the reaction shown below. 4 H₂CrO4 OH Draw the molecule on the…
A: Approach to solving the question: Detailed explanation: Examples: Key references:
Q: What would the effect be on the calculated molar mass if some of the solvent evaporated from…
A: The objective of this question is to understand the effect of solvent evaporation on the calculated…
Q: Between As and Bi, the element with the higher ionization energy is?
A: The objective of the question is to determine which element between Arsenic (As) and Bismuth (Bi)…
Q: None
A: In order to ascertain the quantity of peaks detected in the DEPT-135 (Distortionless Enhancement by…
Q: D ologi Macromolecules entifying the parts of a triacylglycerol Write down the common (not IUPAC)…
A: Hydrolysis of given molecule released the following organic molecules:Note: common name is in…
Q: Convert product C, shown below, into its Fischer projection. One of the carbon atoms has been marked…
A: Step 1:To convert the given product C into its Fischer projection, you need to visualize the…
Q: (a) The 1H-NMR spectrum of compound A, C7H15 Cl, consists of the following signals: 8 1.1 (s, 9H)…
A: Step 1: To determine, we have to determine the structure of the molecule based on the given dataThis…
Q: Based on your ICE table and the equilibrium expression for Ka, set up the expression for Ka in order…
A: Step 1: For number 1, this is called the Neutralization Reaction. Here, the acid and the base will…
Step by step
Solved in 2 steps with 1 images
- R)TheTeactions Ul GTUUP Tand GPoup II with ammonla ahd chlóride ligands give distinctly different compounds to the reactions of the same ligands with transition metals. Explain why this is so. 1) Discuss Werner's theory of coordination complexes and compare that theory to our current understanding of coordination chemistry.Login B Problemn Set Metals and Coordin X online.broward.edu/d2l/le/content/460959/viewContent/12468049/View em Set Metals and Coordination Compounds 7) If you were to use a ligand L that was a stronger field ligand than NH3, what color would you expect the new [NiLs]* complex ion to have? INi(H,O),F* Max absorption in visible=720 nm [Ni(NH),P* Max absorption in visible = 570 nm A) Green B) Blue C) Purple 117. Do you expect any tetragonal (Jahn Teller) distortion of the following complexes. Draw and give the name for each complex. b) [Co(en),(CO),] Cl, a) K[Cr(C,O,)(H,O)(NH;);].3H,O c) [Rh(NO,),(NH;)2](NO3)
- O How can you distinguish cis- and trans- form of K [Cr(C,04);(H,O),] complex by experimentally.Draw the ligand field Walsh correlation diagram for the simultaneous, equal stretching of the top and bottom ligands of an Oh ML6 complex. Label all complexes with point groups, and all orbitals with Mulliken symbols.The ligand-field-stabilization-energies (LFSE) of three pairs of [ML6]** and [ML6]?" complexes are given in the following table. Calculate the difference in LFSE for each pair of reduced and oxidized complexes, that is, the differences in LFSE between [MLs]*" and [MLs]", assuming [ML6]* complexes are low-spin complexes and [ML6J** complexes are high-spin complexes. Arrange the differences in cm' in order of increase in magnitude. A. (cm') [Co(H2O)s]" 16,750 [Co(H;O).J?" [Mn(H20).] 8,400 15,800 [Mn(H2O)s]** 7,850 [Fe(H2O),J** 14,000 [Fe(H2O)«]?* 9,350 A. 5,500 (Fe"/Fe) <9,580 (Mn"/Mn³")< 25,080 (Co"/Co³") B. 5,560 (Fe²"/Fe")<25,080 (Co²"/Co³")< 25,280 (Mn²"/Mn³") C. -20 (Co²"/Co³") <-3,740 (Fe²"/Fe³") < 25,280 (Mn²"/Mn²") D. 24,260 (Fe"/Fe³") < 25,280 (Mn²"/Mn*")< 33,480 (Co"/Co") E. 9,480 (Mn² /Mn³") < 24,260 (Fe²"/Fe³") < 33,480 (Co²"/Co³")
- 7. Do you expect any tetragonal (Jahn Teller) distortion of the following complexes. Draw and give the name for each complex. a) K[Cr(C,O4)(H;0)(NH;)}].3H;O b) [Co(en)2(CO):] Cl2 c) [Rh(NO2)2(NH3)2](NO3)the hexaquanickel(II) has a delta oct of 8,500cm-1. Calculate the CFSE of this complex with your answer as cm-1Help me please
- H3CWCH3 For all complexes listed below, determine the following. (Be sure to label a, b, c, and d clearly). a) metal oxidation state b) total number of electrons contributed by metal c) total number of electrons contributed by ligand set d) total electron count of the complex H3C. CH3 Ph3P, PPH3 Co Rh Ph3P H3C CH3Show all electronic transition in the spectrum of a d3 complex. Scetch the appropriate spectrum.2. When an anhydrous solution of CrCl₂ in EtOH was treated with ligand 1 (below), a precipitate of complex X appeared, and this was filtered off under an atmosphere of nitrogen. A sample of 'hydrated chromium(III) chloride' (actually, [CrCl2(H2O)4]Cl-2H2O) was dissolved in dimethylformamide and boiled (153 °C) to remove water. To the resulting purple solution was added an excess of ligand 1 (below) at 130 °C. On allowing the mixture to cool, a precipitate appeared, complex Y. Analytical and magnetic data for X and Y are given below. Complex X N NH2 1 Complex Y Found: % C=42.4, H = 4.8, N = 16.5, Cl Found: % C = 38.4, H = 4.4, CI = 28.5, = 21.0, Cr 15.5 = Magnetic moment = 4.9 μB Cr = 13.9. Magnetic moment = 3.87 MB a. Explain all the analytical data and the information in the description above, hence deduce possible structures for X and Y. Explain your reasoning. b. What is the likely geometry of the anionic ligands for complex X? Explain your reasoning. C. How many geometric isomers…