QUESTION 1 Sodium bicarbonate (NaHCO3) dissolves in water by the following reaction: NaHCO3 (s) + Na* (aq) + HCO3 (aq) K = 1.3 When dissolved in 100 ml of pure water, equilibrium is achieved when 9.6 g NaHCO3 is added. I then try to dissolve NaHCO3 in other aqueous solutions. Which solution will achieve equilibrium with the least amount of NaHCOz added? O 1.0 M NaCI O 1.0 M KCI O 1.0 M KI QUESTION 2 I want to make a pH buffer with a pH of 9.5. From the following given pka and pkh values, which mixture would be best to do so? (Henderson-Hasselbalch equation: pH = pka + log([base)[acid])) Benzoic acid (C6H5COOH): pKka = 4.19 Pyridine (C5H5N): pKh = 8.77 Ammonia (NH3): pKp = 4.75 1.1 M C5H5N and 0.20 M C5H5NH* O 0.60 M C5H5N 0.50 M C6H5COOH and 1.0 M C6H5C" 0.80 M NH3 and 0.45 M NHA+

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Chapter13: Chemical Equilibrium
Section: Chapter Questions
Problem 3ALQ: For the reactionH2(g)+I2(g)2HI(g), consider two possibilities: (a) you mix 0.5 mole of each...
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QUESTION 1
Sodium bicarbonate (NaHCO3) dissolves in water by the following reaction:
NaHCO3 (s) - Na* (aq) + HCO3 (aq)
Ke = 1.3
When dissolved in 100 ml of pure water, equilibrium is achieved when 9.6 g NaHCO3 is added. I then try to dissolve NaHCO3 in other aqueous solutions. Which solution will achieve equilibrium with the least
amount of NaHCO3 added?
O 1.0 M NaCl
O 1.0 M KCI
O 1.0 M KI
QUESTION 2
I want to make a pH buffer with a pH of 9.5.
From the following given pka and pkh values, which mixture would be best to do so?
(Henderson-Hasselbalch equation: pH = pka + log([base)[acid]))
Benzoic acid (CGH5COOH): pka = 4.19
Pyridine (C5H5N): pKb = 8.77
Ammonia (NH3): pkh = 4.75
1.1 M C5H5N and 0.20 M C5H5NH*
O 0.60 M C5H5N
O 0.50 M C6H5COOH and 1.0 M C6H5C0
0.80 M NH3 and 0.45 M NH4+
Transcribed Image Text:QUESTION 1 Sodium bicarbonate (NaHCO3) dissolves in water by the following reaction: NaHCO3 (s) - Na* (aq) + HCO3 (aq) Ke = 1.3 When dissolved in 100 ml of pure water, equilibrium is achieved when 9.6 g NaHCO3 is added. I then try to dissolve NaHCO3 in other aqueous solutions. Which solution will achieve equilibrium with the least amount of NaHCO3 added? O 1.0 M NaCl O 1.0 M KCI O 1.0 M KI QUESTION 2 I want to make a pH buffer with a pH of 9.5. From the following given pka and pkh values, which mixture would be best to do so? (Henderson-Hasselbalch equation: pH = pka + log([base)[acid])) Benzoic acid (CGH5COOH): pka = 4.19 Pyridine (C5H5N): pKb = 8.77 Ammonia (NH3): pkh = 4.75 1.1 M C5H5N and 0.20 M C5H5NH* O 0.60 M C5H5N O 0.50 M C6H5COOH and 1.0 M C6H5C0 0.80 M NH3 and 0.45 M NH4+
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