
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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i) Explain the acidity of terminal alkanes , alkenes and alkynes.
ii) Compound A has the formula C10H16. On catalytic hydrogenation over palladium, it reacts with only 1 molar equivalent of H2 to yield C. Compound A also undergoes reaction with ozone, followed by zinc treatment, to yield a symmetrical diketone, B (C10H16O2). By showing the reaction steps, predict the structures of A, B and C.
iii) Show the reaction mechanism of cyclohexene with Br2.
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- "A research team synthesizes a novel organic compound 'X' with the molecular formula C5H8O2. When 'X' is treated with a deuterated acid (D2O), a single deuterium atom replaces a hydrogen atom, forming compound 'Y' (C5H7DO2). 'X' does not react with 2,4-Dinitrophenylhydrazine (2,4-DNP) but does react with both Tollens' reagent and Benedict's solution, forming a silver mirror and a red precipitate, respectively. Furthermore, 'X' undergoes catalytic hydrogenation over a palladium catalyst, consuming one mole of hydrogen to form a compound 'Z' (C5H10O2). Based on these observations, what is the most likely structure of compound 'X'?" A. Methyl vinyl ketone B. 3-Buten-2-one C. Acetoacetic ester D. 2-Hydroxypent-3-enalarrow_forwardA compound C3H6O has a hydroxyl group but no doublebonds. Write a structural formula consistent with thisinformation.arrow_forwardOn prolonged storage, the compound shown below reacts to give a product of molecular formula C12H:60. What is the structure of this product? ÇI OH • C:2H10arrow_forward
- Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry. If the product is racemic write racemic or draw both isomers. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state "No Reaction"arrow_forwardCompound X, C,4H12Br2, is optically inactive. On treatment with strong base, X gives hydrocarbon Y, C14H10: Compound Y absorbs 2 equivalents of hydrogen when reduced over a palladium catalyst to give z (C14H14) and reacts with ozone to give one product, benzoic acid (C,Hg02). Draw the structure of compound Z. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Ignore alkene stereochemistry. • If more than one structure fits the description, draw them all. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures with + signs from the drop-down menu. ChemDoodlearrow_forward(S)-2-butanol reacts with potassium dichromate (K2CrO4) in aqueous sulfuric acid to give A(C4H3O). Treatment of A with ethylmagnesium bromide in anhydrous ether gives B(C,H140). Draw the structure of B.arrow_forward
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