Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- The rate law for the reaction in Exercise E17A.4(b) was reported as d[C]/dt = kr[A][B][C]−1. Express the rate law in terms of the reaction rate v. What are the units of kr when the concentrations are in moles per cubic decimetre?arrow_forwardThe half-life of a biologically degraded contaminant is 1 h. Therefore, the kinetic constant of the reaction is most nearly (A) 17/d (В) 24/d (С) 73/d (D) 96/darrow_forwardConsider a second order reaction where ? → ?. The reaction is performed in a batch reactorwhere the concentration of component A decreases from CA0=2.03 mol/L to CA=1.97 mol/L inone minute. What is the reaction constant of this second order reactionarrow_forward
- What is the concentration of A after 20.5 minutes for the reaction A → Products when the initial concentration of A is 0.800 M? (k = 0.00651 M/min)arrow_forward(a) Consider the mass transfer-limited reaction: A → 2B DAB = 0.01 cm²s-1 What would your concentration (mole fraction) profile look like as a function of distance (i.e. z/8)? What is the flux of A?arrow_forwardPlease help!!!arrow_forward
- The kinetics of the hydrolysis of methyl methanoate, CH;COOCH;, in aqueous solution were investigated by measuring the concentration of the ester after different time intervals. The reaction was found to be first order in the concentration of the ester. Use the data below to determine the rate constant for the reaction. time (t/s) concentration (c/mol.dm-3) 1800 3600 5400 7200 9000 0.300 0.191 0.135 0.081 0.055 0.035arrow_forwardProblem IX (10 p): Consider the isomerization of compound A from its cis to its trans isomer at 298 K, which is first order in both directions: ki cis-A = trans-A k2 The rate constant for the forward reaction is k1 = 4.2 × 10* s', and the rate constant for the reverse reaction is k2 = 2.1 × 10-ª s-1. %3D a) Calculate the equilibrium concentrations [cis-A]eq and [trans-A]eq, assuming that at time t= 0 all of A was in the cis-form, i.e., [cis-A]o = [A]o. (Hint: Use the fact that at any time, [cis-A] + [trans-A] = [A]o.) %3D b) Which reaction is spontaneous, the forward reaction or the reverse reaction? Provide your reasoning. Total /100 parrow_forwardThe rate of a certain reaction is given by the following rate law: rate =kNO2O2 Use this information to answer the questions below. What is the reaction order in NO? What is the reaction order in O2? What is overall reaction order? At a certain concentration of NO and O2, the initial rate of reaction is 5.0 x 104 M / s. What would the initial rate of the reaction be if the concentration of NO were doubled? Be sure your answer has the correct number of significant digits. Ms The rate of the reaction is measured to be 40.0 M / s when [NO] = 0.57 M and [O2] = 2.0 M. Calculate the value of the rate constant. Be sure your answer has the correct number of significant digits. =k⋅M−2s−1arrow_forward
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