Provide a synthesis for the target molecule shown below, starting with an alkyl halide or alcohol of your choice. In each case, showyour retrosynthetic analysis, and then provide a complete synthesis, showing all necessary reagents.{Which of the following syntheses are suitable to prepare the given target molecule (as the major product formed)? Select all that apply.000O1) TsCl, pyridineOH 2) NaOEtOH-CI1) TsCl, pyridine2)1-BuOKNaOHt-BuOKconc. H₂SO4PotsOHheatt-BuOK

Answered: Image /qna-images/answer/3c61a07c-3311-4a36-b9f9-8e1640b8f5f6.jpg

Answered: Provide a synthesis for the target…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Starting with benzene and using any other reagents of your choice, design a synthesis for the following compound: COOH NO₂ COOH The target molecule above can be prepared by treating benzene with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A Mel, AlCl3 B KMnO4, NaOH, heat (followed by H3O+ workup) C HCI, Zn D E F (CH3)2CHCI, AICI 3 HNO3, H2SO4 Fuming H2SO4
Provide a synthesis for the target molecule shown below, starting with an alkyl halide or alcohol of your choice. In each case, show your retrosynthetic analysis, and then provide a complete synthesis, showing all necessary reagents. Which of the following syntheses are suitable to prepare the given target molecule (as the major product formed)? Select all that apply. U U U 3 Br Br t-BUOK OH Br t-BuOK NaOH LOH conc. H₂SO4 heat Br NaOEt conc. H₂SO4 heat
organolithium reagents are strong bases. Because of this, they cannot be prepared from compounds that contain acidic groups (-OH, -NH:, -NHR, -SH, -C=CH, RCO:H) or compounds that have carbonyl groups. Which of the given syntheses of a Grignard reagent below would fail to form as written? Circle the answer and explain your choice Br Mg, ether MgBr 1) Mg, ether Mgl 2) Br Mg. ether MgBr 3) но но 2. Predict the major products for the following reactions with the correct stereochemistry were necessary. SOCI, LOH OH OH SOCI NBS ight NBS G light Me (CH, Cel Br MgBr
Using Ethylene, C2H4, and methyl bromide, CH3Br, as your sole sources of carbon, propose a synthesis for t-BuOH, (CH3)3COH. *the synthesis should take about 7 steps and will include an alkylation and a Grignard reaction. Use one equivalent of methyl bromide for the alkylation step and use the second one to make the Grignard reagent. The substrate in the Grignard reaction will be a carbonyl - make this from your alkyne AFTER alkylation. *show all reactants and intermediates H +2 H H Br -7 steps H₂C H₂C OH CH3
Provide a synthesis for the target molecule shown below, starting with an alkyl halide or alcohol of your choice. In each case, show your retrosynthetic analysis, and then provide a complete synthesis, showing all necessary reagents. Which of the following syntheses are suitable to prepare the given target molecule (as the major product formed)? Select all that apply. ☐ ☐ Br HO Br HO Br HO t-BUOK conc. H₂SO4 heat NaOH 1) TSCI, pyridine 2) NaOH NaOH t-BUOK 1) TSCI, pyridine 2) t-BUOK
Provide a synthesis for the target molecule shown below, starting with compounds that contain no more than two carbon atoms. Show your retrosynthetic analysis, and then provide a complete synthesis, showing all necessary reagents.
Starting with benzene and using any other reagents of your choice, design a synthesis for the following compound: OEt CI & NO₂ The target molecule above can be prepared by treating benzene with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A 1) EtMgBr 2) H₂O¹ D NaOEt, heat B HNO₂, H₂SO4 E NaOH, heat C D F Cl₂, AICI CH-CH₂COCI, AICI
7) Using the carbon-containing starting material(s), propose a synthesis the following retrosynthetic analysis. Provide structures for all intermediates. The carbon atoms in the product must originate from the starting material(s), but you may use as many equivalents of each starting material as you would like, and any reagent/reaction you know (note: no mechanisms are required). Br OH racemic = = + -Br
Propose a sequence of reactions to prepare the specified target compound from the indicated starting materials. All of the carbon atoms in the target must originate in the specified starting materials. Keeping this restriction in mind, you may use any other organic or inorganic reagents necessary to complete the synthesis. It is only necessary to show the overall transformations involved in your proposed synthesis.
Identify the reagents you would use to perform the following transformation: Bromocyclohexane →→ Cyclohexanecarboxylic acid The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A. H3O+, heat D. 1) CO2; 2) H3O+ B. Na₂Cr₂O7, H₂SO4, H₂O E. PCC or DMP C. NaCN F. Mg
Propose a synthesis of 3-hexanone starting from acetylene and any other necessary reagents. Be sure to show all reagents and intermediates along the way.
Draw a possible forward synthesis to form the following compounds using MeOH, ETOH, NaCN and benzene as the only carbon sources. You can use any other reagents so long as they are not a source of carbon in the target molecule. A synthesis may use any previous compound as a reagent. Use retrosynthetic analysis to help. There may be more than one correct answer to each problem. НО Но OH j) k) h) HN

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