Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- Exercise 7.2.1: Heat from a generic reaction. A balance stoichiometric reaction 2D + 0.5E 3.8F with Ah-(100°C, 1 atm) = -48 kJ/mol. (a) If 62 mol/s of component F are produced at 100°C and 1 atm, how much heat (kW) is produced by the reaction?arrow_forward***** Calculate the amount of heat required to convert 20.0 g of ice (HC = 0.5 cal/g/oC) at -10.0 oC to steam (HC = 0.5 cal/g/oC) at 120 oC given that the fusion of water needs 80.0 cal/g and its vaporization needs 540 cal/g.arrow_forwardConsider the reaction of aluminum metal with hydrochloric acid. 2 Al(s) + 6 HCl(aq) → 2 AlCl3(aq) + 3 H₂(g) When 5.00 g of aluminum is added to an excess of hydrochloric acid, all at a constant pressure of 1 atm and a constant temperature of 298 K, the system expels 99.8 kJ of heat into the surroundings. O Calculate the number of moles of hydrogen gas that are produced. Assume that the heat is exchanged without a change in temperature. calculate the amount of work done by the system when the hydrogen gas expands against a constant-pressure atmosphere of 1 atm at 298 K. (Use R = 8.314 x 10³ kJ mol-¹ K-¹.) Use the sign conventions of heat and work and the First Law of Thermodynamics calculate the change in internal energy of the system.arrow_forward
- Potassium fluotitanate (K₂TiF₆), a starting material forproducing other titanium salts, is made by dissolvingtitanium(IV) oxide in concentrated HF, adding aqueous KF, andthen heating to dryness to drive off excess HF. The impure solidis recrystallized by dissolving in hot water and then cooling to 0°C, which leaves excess KF in solution. For the reaction of 5.00 g of TiO₂, 250. mL of hot water is used to recrystallize theproduct. How many grams of purified K₂TiF₆ are obtained?(Solubility of K₂TiF₆ in water at 0°C is 0.60 g/100)arrow_forwardReview | Constants | PeriIodic Table The standard heat of formation, Ar H°, is defined as the enthalpy change for the formation of one mole of substance from its constituent elements in their standard states. Thus, elements in their standard states have AfH® =0. Heat of formation values can be used to calculate the enthalpy change of any reaction. Part A For which of the following reactions is A,H° equal to Ar H° of the product(s)? Consider, for example, the reaction You do not need to look up any values to answer this question. 2NO(g) + O2(9) = 2NO2(9) Check all that apply. with heat of formation values given by the following table: • View Available Hint(s) Substance (kJ mol-1) NO(9) O C(s) + 02 (9)→CO2(9) 90.2 O2 (9) O Li(s) + F2(1)→LIF(s) NO2(9) 33.2 O Li(s) + F2(9)→LİF(s) O 2Li(s) +F2(9)→2LİF(s) Then the heat of formation for the overall reaction is A,H°= EnpAf H° (products)- nA¢H° (reactants) O CO(g) + ÷O2(9)→CO2(9) 2(33.2) [2(90.2) + 0] -114 kJ mol-1 O BaCO3(s)→BA0(s) + CO2(9)…arrow_forwardLiquid gas undergoes combustion in air, releasing 100kf of heat and producing two gaseous products. Include energy in the reaction. When HCL reacts with NaOH to produce NaCl and H2O, 60kj of heat is released in the surroundings. a. State whether the surrounding gets warmer or colder. b. Sketch a PE graph for this reaction.arrow_forward
- Ammonia is oxidized in a continuous reactor 4NH3 g + 5O2 g --> 4NO g + 6H2O g delta AHr= -904.7KJ mol The feed stream (40 mole% NH3 and 60 mole% O2 )enters the reactor at 200 degrees celsius with 80% conversion of ammonia and the products leave at 300 degrees celsius. Determine the quantity of heat required to be added or removed from the reactor.arrow_forwardUse the chemical reaction below to answer the following questions HCI(aq) + NaOH(aq) → NaCl (aq) + H2O (I) AH298 = -58 kJ/mol (a) How much heat is produced when 200 mL of 0.3 M HCL (density = 1.00 g/mL) and 250 mL of 0.25 M NaOH (density = 1.00 g/mL) are mixed? (b) If both of the solutions at the same temperature and the heat capacity of the products are 5.39 J/g °C , how much will the temperature increase? (c) What assumptions are made when calculating your answersarrow_forwardAmmonia is oxidized in a continuous reactor 4NH3 g + 5O2 g --> 4NO g + 6H2O g delta AHr= -904.7KJ mol The feed stream (40 mole% NH3 and 60 mole% O2 )enters the reactor at 200 degrees celsius with 80% conversion of ammonia and the products leave at 300 degrees celsius. Determine the quantity of heat required to be added or removed from the reactor. The basis of calculation: 10mol/s of feed stream. given: the constant heat capacity, Cp, of NH3(g), O2(g), NO(g), and H2O(v) are 0.035, 0.029, 0.029 and 0.033KJ/ mol. degrees celsius respectively.) Cp O2 or table 8 for the calculation. can you please explaing each steparrow_forward
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