Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- (2) Calculate the heat of reaction at 298K for the following reactions a) 3NO2(g) + H₂O(0) b) C3Hs (g) +02 (8) c) CaCO3(s) 2HNO3(+NO(g) ►CO2(g) + H₂O(n CaO(s)+COz(g)arrow_forwardThe equilibrium constant with respect to temperature can be expressed for the reaction: Cyclohexane (g)! <--> methylcyclopentane (g) as: LnK = 4.814-2059/T. If placed to react 3 moles cyclohexane in a 5 liter container at a certain temperature and when equilibrium is reached, 8000 J of heat is released, Calculate the temperature of the container.arrow_forward***** Calculate the amount of heat required to convert 20.0 g of ice (HC = 0.5 cal/g/oC) at -10.0 oC to steam (HC = 0.5 cal/g/oC) at 120 oC given that the fusion of water needs 80.0 cal/g and its vaporization needs 540 cal/g.arrow_forward
- The reaction of carbon monoxide(g) with water(l) to form carbon dioxide(g) and hydrogen(g) proceeds as follows: CO(g) + H2O(l) ---> CO2(g) + H2(g) When 10.2 grams of CO(g) react with sufficient H2O(l) , 1.02 kJ of energy are absorbed .What is the value of H for the chemical equation given?arrow_forward(d) Determine the weight percentage, wt%, of the solid solution and liquid solution of a Cu-Ni alloy with a composition of 21 % Ni 79 % Cu, at a temperature of 1050 °C. Use part of the Thermal Equilibrium Diagram for Copper (Cu)-Nickel (Ni) alloy, as shown in Figure 1. Clearly show all your calculations. Temperature "C Figure 1 Part of the Cu-Ni thermal equilibrium diagram (not to scale) 1050 11 21 29 % Niarrow_forwardThe fuel in the form of biogas (65%-mol CH4 and 35%-mol CO2) is burned in a furnace. In order for combustion to take place stoichiometrically, calculate the air to fuel ratio (vol/vol) from this problem!arrow_forward
- Question: Consider the sugar–water phase diagram of Figure 10.1. (a) How much sugar will dissolve in 1000 g of water at 80°C (176°F)? (b) If the saturated liquid solution in part (a) is cooled to 20°C (68°F), some of the sugar will precipitate out as a solid. What will be the composition of the saturated liquid solution (in wt% sugar) at 20°C? (c) How much of the solid sugar will come out of the solution upon cooling to 20°C? Figure 10.1 is provided below.arrow_forward4. At 1084 °C solid copper melts to form a liquid. The phase change can be described as Cu(s) → Cu(t). The density of solid and liquid copper are 8.96 g/cm' and 7.75 g/cm' respectively. The enthalpies of combustion of the solid and liquid are -156.06 kJ/mol and -167.92 kJ/mol respectively. The product of combustion of both the solid and liquid is CuO(s). Calculate the standard enthalpy changes for the fusion process in kJ/mol. Calculate the change in internal energy when the sample is under a pressure of 500 kbar. Cu(s) → Cu(e) Solid copper liquid copper enthalples of combustion 8.96 g/cm3 7.75 g 1cm² said: -156.06 kJ/mol liquid-162.42 kJ/molarrow_forward
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