Predicting color and magnetic properties from a crystal field theory ener... 2+ When a certain weak-field ligand forms an octahedral complex with Zn cation, the energies of the valence d orbitals on the zinc atom are split according to this electron box diagram: energy in kJ/mol -350 -400 -450 -500 2 2 2 Z x-y -550 -600 -650 -700 -750 xy yz XZ -800 Using this diagram, answer the following questions. How many unpaired d electron spins does the zinc atom have? Is the complex paramagnetic or diamagnetic? Predict the color of the complex. ☐ paramagnetic diamagnetic blue or green red or violet orange or yellow white or transparent OL E 9
Predicting color and magnetic properties from a crystal field theory ener... 2+ When a certain weak-field ligand forms an octahedral complex with Zn cation, the energies of the valence d orbitals on the zinc atom are split according to this electron box diagram: energy in kJ/mol -350 -400 -450 -500 2 2 2 Z x-y -550 -600 -650 -700 -750 xy yz XZ -800 Using this diagram, answer the following questions. How many unpaired d electron spins does the zinc atom have? Is the complex paramagnetic or diamagnetic? Predict the color of the complex. ☐ paramagnetic diamagnetic blue or green red or violet orange or yellow white or transparent OL E 9
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Predicting color and magnetic properties from a crystal field theory ener...
2+
When a certain weak-field ligand forms an octahedral complex with Zn cation, the energies of the valence d orbitals on the zinc atom are split according to
this electron box diagram:
energy in kJ/mol
-350
-400
-450
-500
2
2 2
Z
x-y
-550
-600
-650
-700
-750
xy
yz
XZ
-800
Using this diagram, answer the following questions.
How many unpaired d electron spins does the zinc atom have?
Is the complex paramagnetic or diamagnetic?
Predict the color of the complex.
☐
paramagnetic
diamagnetic
blue or green
red or violet
orange or yellow
white or transparent
OL
E
9
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