Predict whether these complexes would be labile or inert and explain your choices. The magnetic moments are given in Bohr magneton (BM) after each compound.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section20.7: Crystal-field Theory: Color And Magnetism In Coordination Compounds
Problem 20.10PSP
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a) Predict whether these complexes would be labile or inert and explain your choices. The
magnetic moments are given in Bohr magneton (BM) after each compound.
Magnetic moment
in Bohr magneton
Compound
Potassium hexaiodomanganate (IV)
3.82
Hexaammine iron (II) chloride
5.45
b) The high-spin dt complex [Cr(H:O)s]* is labile, but the low-spin đº complex ion
[Cr(CN)6]+ is inert. Explain
c) Calculate the orbital multiplicity for a Cr* assuming it is a free ion (Not complex).
BIU O
A
2
!!!
Transcribed Image Text:a) Predict whether these complexes would be labile or inert and explain your choices. The magnetic moments are given in Bohr magneton (BM) after each compound. Magnetic moment in Bohr magneton Compound Potassium hexaiodomanganate (IV) 3.82 Hexaammine iron (II) chloride 5.45 b) The high-spin dt complex [Cr(H:O)s]* is labile, but the low-spin đº complex ion [Cr(CN)6]+ is inert. Explain c) Calculate the orbital multiplicity for a Cr* assuming it is a free ion (Not complex). BIU O A 2 !!!
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