Specialized reagents and their acronyms: MCPBA= meta-chloroperbenzoic acid; HOAC = aceticacid, NaOAc = Sodium Acetate; Ph= phenyl = C6H5-; P(Ph)3 = triphenyl phosphine; NBS = N-bromosuccinimide, PBr3, SOCI2, AICI3, FeBr3, H2SO4, Li, Na, Mg, Br2, CrO3, LDA = lithiumdiisopropylamide, PCC = pyridinium chlorochromate, KO-C(CH3)3, LAH = LIAIH4, (sia)2BH =disecondary isobutyl borane, KMNO4, HIO4 = periodic acid%3D%3D%3D%3D%3Dwrite the missing reagents and solvents over the arrows. Some transformation requiremultiple steps. In some cases there will be multiple arrows.PhCHCHo 0om ilubongoCEC-PhIn questions 14-24, write the products of the following transformations. If there is no reactionwrite NR. Indicate R or S or racemic or indicate cis or trans where appropriateOH+ LDATHF solvent(S)Ph

“Since you have asked multiple question, we will solve the first question for you. If you want any…

Answered: Ph. CH CH EC-Ph

Science

Chemistry

Ph. CH CH EC-Ph

Introduction to General, Organic and Biochemistry

11th Edition

ISBN:9781285869759

Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Chapter18: Carboxylic Acids

Section: Chapter Questions

Problem 18.54P

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Question

Specialized reagents and their acronyms: MCPBA= meta-chloroperbenzoic acid; HOAC = acetic
acid, NaOAc = Sodium Acetate; Ph= phenyl = C6H5-; P(Ph)3 = triphenyl phosphine; NBS = N-
bromosuccinimide, PBr3, SOCI2, AICI3, FeBr3, H2SO4, Li, Na, Mg, Br2, CrO3, LDA = lithium
diisopropylamide, PCC = pyridinium chlorochromate, KO-C(CH3)3, LAH = LIAIH4, (sia)2BH =
disecondary isobutyl borane, KMNO4, HIO4 = periodic acid
%3D
%3D
%3D
%3D
%3D
write the missing reagents and solvents over the arrows. Some transformation require
multiple steps. In some cases there will be multiple arrows.
Ph
CH
CH
o 0om ilubongo
CEC-Ph
In questions 14-24, write the products of the following transformations. If there is no reaction
write NR. Indicate R or S or racemic or indicate cis or trans where appropriate
OH
+ LDA
THF solvent
(S)
Ph

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