Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- When a solid dissolves in water, heat may be evolved or absorbed. The heat of dissolution (dissolving) can be determined using a coffee cup calorimeter. In the laboratory a general chemistry student finds that when 0.90 g of CaCl2(s) are dissolved in 102.10 g of water, the temperature of the solution increases from 22.90 to 24.48 °C. The heat capacity of the calorimeter (sometimes referred to as the calorimeter constant) was determined in a separate experiment to be 1.79 J/°C.Based on the student's observation, calculate the enthalpy of dissolution of CaCl2(s) in kJ/mol. Assume the specific heat of the solution is equal to the specific heat of water.ΔHdissolution = kJ/molarrow_forwardA candy bar has a total mass of 75.0 grams. In a calorimetry experiment, a 1.25-g sample of this candy bar was burned in a calorimeter surrounded by 1000 g of water. The temperature of the water in contact with the burning candy bar was measured and found to increase from an initial temperature of 21.2°C to a final temperature of 24.3°C. a. Calculate the amount of heat in calories released when the 1.25-g sample burned. (show the work you did)arrow_forwardA 1.261 g sample of a new organic material is combusted in a bomb calorimeter. The temperature of the calorimeter and its contents increase from 25.39 °C to 28.44 °C. The heat capacity (calorimeter constant) of the calorimeter is 27.69 kJ/ °C, what is the heat of combustion per gram of the material? heat of combustion: kJ/garrow_forward
- In a coffee cup calorimeter, 50.0 mL of 1.00 M NaOH and 50.00 mL of 1.00 M HCl are mixed. Both solutions were originally at 24.6 C. After the reaction, the final temperature is 31.3 C. Given that the density of NaCl solution is 1.038 g/mL and the specific heat of NaCl solution is 3.87, calculate the change in enthalpy of neutralization per mole for the reaction of HCl with NaOH. Assume that no heat is lost to the surroundings.arrow_forwardThe following thermochemical equation is for the reaction of hydrogen chloride(g) with ammonia(g) to form ammonium chloride(s). HCl(g) + NH3(g) --> NH4Cl(s) ΔH = -176kJ How many grams of HCl(g) would have to react to produce 45.2 kJ of energy? _______ gramsarrow_forwardPlease don't provide handwritten solution ....arrow_forward
- When 1.836 grams of sucrose (Molar mass 342.3 g/mol) is burned in a bomb calorimeter, the temperature of the calorimeter increases from 22.41°C to 26.63°C. If the heat capacity of the calorimeter is 4.900 kJ/°C, what is the heat of combustion of sucrose?arrow_forwardThe complete combustion of salicylic acid releases 21.90 kJ of energy per gram of salicylic acid.In a particular bomb calorimeter (initially at room temperature), the combustion of 0.2745 g of salicylic acid, in the presence of excess oxygen, causes the temperature of the calorimeter to rise by 1.85 °C.When a 0.2999-g sample of an unknown organic substance is similarly burned in the same calorimeter, the temperature rises by 3.59 °C.What is the energy of combustion per unit mass of the unknown substance?arrow_forwardWhen a solid dissolves in water, heat may be evolved or absorbed. The heat of dissolution (dissolving) can be determined using a coffee cup calorimeter. In the laboratory a general chemistry student finds that when 0.79 g of KOH(s) are dissolved in 104.10 g of water, the temperature of the solution increases from 24.69 to 26.63 °C. The heat capacity of the calorimeter (sometimes referred to as the calorimeter constant) was determined in a separate experiment to be 1.58 J/°C. Based on the student's observation, calculate the enthalpy of dissolution of KOH(s) in kJ/mol. Assume the specific heat of the solution is equal to the specific heat of water. kJ/mol AH dissolution = BrookaCom Cengage Leaming Thermometer Cardboard or Styrofoam lid Nested Styrofoam cups Reaction occurs in solution.arrow_forward
- When a solid dissolves in water, heat may be evolved or absorbed. The heat of dissolution (dissolving) can be determined using a coffee cup calorimeter. In the laboratory a general chemistry student finds that when 3.95 g of CuCl2(s) are dissolved in 108.60 g of water, the temperature of the solution increases from 23.05 to 26.27 °C. The heat capacity of the calorimeter (sometimes referred to as the calorimeter constant) was determined in a separate experiment to be 1.86 J/°C. Based on the student's observation, calculate the enthalpy of dissolution of CuCl,(s) in kJ/mol. Assume the specific heat of the solution is equal to the specific heat of water. AHdissolution kJ/molarrow_forwardWhen 3.50 g of sodium hydroxide (NaOH) was dissolved in 50.00 g of water a value of 9.50oC was obtained for ΔT. Calculate the value (calories) for the heat of solution of 3.50 g of NaOH. Calculate the number of calories that would be produced if one mole of sodium hydroxide was dissolved. (ΔHsolnNaOH)arrow_forwardConsider these reactions: Reaction 1: H2 (g) + Cl2 (g) → 2HC1(g) AH = -184.6 kJ Reaction 2: 20F2 (9) → 02 (9) + 2 F2 (9) AH= -49.4 kJ Reaction 3: N2 (g) + 202(g) → 2NO2(g) AH=+66.4 kJ Use Reaction 2. How much energy (in kJ) is released when 61.0 g of oxygen difluoride decomposes? Answer: - kJ (enter a positive value)arrow_forward
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