
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- For the galvanic (voltaic) cell Fe(s) + Mn²⁺(aq) ⟶ Fe²⁺(aq) + Mn(s) (E° = 0.77 V at 25 °C), what is [Fe²⁺] if [Mn²⁺] = 0.030 M and E = 0.78 V? Assume T is 298 Karrow_forwardFor the electrochemical cell 2 Al(s) + 3 Mn²⁺(aq) ⟶ 2 Al³⁺(aq) + 3 Mn(s) (E° = 0.48 V, [Al³⁺] = 1.0 M), what is the value of E when [ Mn²⁺] = 0.089 M? Assume T is 298 Karrow_forwardFor the electrochemical cell 2 Al(s) + 3 Mn²⁺(aq) ⟶ 2 Al³⁺(aq) + 3 Mn(s) (E° = 0.48 V, [Al³⁺] = 1.0 M), what is the value of E when [ Mn²⁺] = 0.018 M? Assume T is 298 Karrow_forward
- A student wishes to determine the chloride ion concentration in a water sample at 25 °C using a galvanic cell constructed with a graphite electrode and a half-cell of AgCI(s) + e¯ → Ag(s) + Cl¯(aq) E°red = 0.2223 V And a copper electrode with 0.500 M Cu²* as the second half cell Cu2*(aq) + 2 e → Cu(s) E°red= 0.337 V The measured cell potential when the water sample was placed into the silver side of the cell was 0.0903 V. What is the standard cell potential for this cell in V?arrow_forwardFor the galvanic (voltaic) cell Cd²⁺(aq) + Fe(s) ⟶ Cd(s) + Fe²⁺(aq) (E° = 0.0400 V), what is the ratio [Fe²⁺]/[Cd²⁺] when E = 0.000 V? Assume T is 298 Karrow_forwardWhen the Pb²+ concentration is 1.14 M, the observed cell potential at 298 K for an electrochemical cell with the following reaction is 1.154 V. What is the Mn²+ concentration? 2+ Pb²+ (aq) + Mn(s) → Pb(s) + Mn²+ (aq) 2+ Pb²+ (aq) + 2e¯¯ → Pb(s) Fre (aq) + 2e¯ → Mn(s) E Mn²+ red 2+ Mn²+] = M -0.126 V -1.180 Varrow_forward
- For the galvanic (voltaic) cell Cd²⁺(aq) + Fe(s) ⟶ Cd(s) + Fe²⁺(aq) (E° = 0.0400 V), what is the ratio [Fe²⁺]/[Cd²⁺] when E = 0.010 V? Assume T is 298 Karrow_forwardFor the galvanic (voltaic) cell Cd²⁺(aq) + Fe(s) ⟶ Cd(s) + Fe²⁺(aq) (E° = 0.0400 V), what is the ratio [Fe²⁺]/[Cd²⁺] when E = 0.001 V? Assume T is 298 Karrow_forwardConsider the following electrochemical cell at 298 K where the source of Cu2+ (aq) is the sparingly soluble salt CuX. Zn(s)|Zn²* (aq, 0.50M)||Cu²+ (aq)|Cu(s) Zn2* + 2e = Zn E° = -0.76 V Cu2+ + 2e = Cu E° = 0.34 V If the potential created from this cell = 1.03 V, what is Ksp for CuX? O 1.9x10-9 3.8x10 12 4.6x10 6 2.0x10 7arrow_forward
- For the electrochemical cell 2 Al(s) + 3 Mn²+ (aq) → 2 Al³+ (aq) + 3 Mn(s) (E° = 0.48 V, [A1³] = 1.0 M), what is the value of E when [Mn²+] = 0.026 M? Assume T is 298 Karrow_forwardFor the electrochemical cell 2 Al(s) + 3 Mn²⁺(aq) ⟶ 2 Al³⁺(aq) + 3 Mn(s) (E° = 0.48 V, [Al³⁺] = 1.0 M), what is the value of E when [ Mn²⁺] = 0.075 M? Assume T is 298 Karrow_forward
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