One way to reduce the presence of lead in water is to add a phosphate corrosion inhibitor, which forms an insoluble saltwith lead, coating the pipes with a protective mineral later: Pb3(PO4)2(s) ⇌ 3Pb2+(aq) + 2PO43-(aq)      Kc=9.9 x 10-55 a.) Calculate the solubility of lead (Pb2+) in g/L when Pb3(PO4)2 is dissolved in water. b.) The acceptable level of lead in water is less than 1x10-6g/L. If phosphate is added to drinking water, does it keep the lead levels below the allowed limit? c.) In 2014, the city of Flint, MI, changed water sources to a system that didn’t include phosphate. Instead, it used chlorine to treat water. The Ksp of lead chloride is 1.5x10-5. The switch increased the levels of lead in the drinking water and significantly affected the community. Explain why switching water sources increased the lead levels in Flint’s drinking water.

General Chemistry - Standalone book (MindTap Course List)
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ISBN:9781305580343
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Chapter17: Solubility And Complex-ion Equilibria
Section: Chapter Questions
Problem 17.123QP
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One way to reduce the presence of lead in water is to add a phosphate corrosion inhibitor, which forms an insoluble saltwith lead, coating the pipes with a protective mineral later:

Pb3(PO4)2(s) ⇌ 3Pb2+(aq) + 2PO43-(aq)      Kc=9.9 x 10-55

a.) Calculate the solubility of lead (Pb2+) in g/L when Pb3(PO4)2 is dissolved in water.

b.) The acceptable level of lead in water is less than 1x10-6g/L. If phosphate is added to drinking water, does it keep the lead levels below the allowed limit?

c.) In 2014, the city of Flint, MI, changed water sources to a system that didn’t include phosphate. Instead, it used chlorine to treat water. The Ksp of lead chloride is 1.5x10-5. The switch increased the levels of lead in the drinking water and significantly affected the community. Explain why switching water sources increased the lead levels in Flint’s drinking water. 

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