On a separate sheet of paper, draw the two alternative chair conformations for the product formed by the addition of bromine to 4-tert-butylcyclohexene. The Gibbs free-energy differences between equatorial and axial substituents on a cyclohexane ring are 21 kJ/mol for tert-butyl, and 2.3 kJ/mol for bromine. Calculate the ratio of the two observed products at 46.0 °C using the following equation: AG-RT ln Keq The gas constant, R, is 8.314 J/K-mol. (Enter your answer to two significant figures.) Ratio: Major to 1 Minor
On a separate sheet of paper, draw the two alternative chair conformations for the product formed by the addition of bromine to 4-tert-butylcyclohexene. The Gibbs free-energy differences between equatorial and axial substituents on a cyclohexane ring are 21 kJ/mol for tert-butyl, and 2.3 kJ/mol for bromine. Calculate the ratio of the two observed products at 46.0 °C using the following equation: AG-RT ln Keq The gas constant, R, is 8.314 J/K-mol. (Enter your answer to two significant figures.) Ratio: Major to 1 Minor
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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