Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Given the NMR spectra, what is the compound?

**Chemical Structures and NMR Spectrum Analysis**

This image shows four distinct chemical structures labeled I, II, III, and IV, followed by an NMR spectrum. Let's analyze each component:

**Chemical Structures:**

1. **Structure I**:
   - Aniline derivative with ortho-methyl and para-amino groups.
   - Chemical formula: C7H9N
   - Structural features: Benzene ring with NH2 at para position and CH3 at ortho position.

2. **Structure II**:
   - Aniline derivative with meta-methyl and para-amino groups.
   - Chemical formula: C7H9N
   - Structural features: Benzene ring with NH2 at para position and CH3 at meta position.

3. **Structure III**:
   - Alkylamine with an ethyl chain and an NH group.
   - Chemical formula: C8H11N
   - Structural features: Benzene ring with ethylamine substituent.

4. **Structure IV**:
   - N-ethyl aniline derivative with a para-methyl group.
   - Chemical formula: C9H13N
   - Structural features: Benzene ring with an N-ethylmethylamino group.

**NMR Spectrum:**

The NMR spectrum at the bottom of the image shows several peaks over a chemical shift range of 0-200 ppm. The key spectral details include:

- Peaks between 0-50 ppm: Likely represent aliphatic carbons.
- Peaks around 120 ppm: Characteristic of aromatic carbons.
- Large peak near 140 ppm: Suggests substituted aromatic carbons.

This analysis will help students understand the relationship between molecular structure and NMR data, providing insights into interpreting spectral information in organic chemistry.
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Transcribed Image Text:**Chemical Structures and NMR Spectrum Analysis** This image shows four distinct chemical structures labeled I, II, III, and IV, followed by an NMR spectrum. Let's analyze each component: **Chemical Structures:** 1. **Structure I**: - Aniline derivative with ortho-methyl and para-amino groups. - Chemical formula: C7H9N - Structural features: Benzene ring with NH2 at para position and CH3 at ortho position. 2. **Structure II**: - Aniline derivative with meta-methyl and para-amino groups. - Chemical formula: C7H9N - Structural features: Benzene ring with NH2 at para position and CH3 at meta position. 3. **Structure III**: - Alkylamine with an ethyl chain and an NH group. - Chemical formula: C8H11N - Structural features: Benzene ring with ethylamine substituent. 4. **Structure IV**: - N-ethyl aniline derivative with a para-methyl group. - Chemical formula: C9H13N - Structural features: Benzene ring with an N-ethylmethylamino group. **NMR Spectrum:** The NMR spectrum at the bottom of the image shows several peaks over a chemical shift range of 0-200 ppm. The key spectral details include: - Peaks between 0-50 ppm: Likely represent aliphatic carbons. - Peaks around 120 ppm: Characteristic of aromatic carbons. - Large peak near 140 ppm: Suggests substituted aromatic carbons. This analysis will help students understand the relationship between molecular structure and NMR data, providing insights into interpreting spectral information in organic chemistry.
### NMR Spectrum Analysis

The image shows an NMR (Nuclear Magnetic Resonance) spectrum graph, commonly used in chemistry to determine the structure of organic compounds. 

#### Graph Details:
- **X-Axis**: Labeled "ppm" (parts per million), this represents the chemical shift, which indicates the environment of the hydrogen atoms in the molecule.
- **Y-Axis**: Typically represents signal intensity, though not explicitly labeled here.
- **Peaks**: There are distinct peaks at approximately 7.5 ppm, 3.5 ppm, and 1.2 ppm. Each peak corresponds to a different type of hydrogen environment in the analyzed compound.

#### Multiple Choice Section:
- The options below the graph are unlabeled circles with Roman numerals:
  - ○ I
  - ○ II
  - ○ III
  - ○ IV

These options might correspond to possible answers related to the analysis of the NMR spectrum or different compounds potentially being analyzed.

This graph serves as a fundamental tool for students and researchers in organic chemistry to infer the structure of molecules based on their hydrogen environments.
expand button
Transcribed Image Text:### NMR Spectrum Analysis The image shows an NMR (Nuclear Magnetic Resonance) spectrum graph, commonly used in chemistry to determine the structure of organic compounds. #### Graph Details: - **X-Axis**: Labeled "ppm" (parts per million), this represents the chemical shift, which indicates the environment of the hydrogen atoms in the molecule. - **Y-Axis**: Typically represents signal intensity, though not explicitly labeled here. - **Peaks**: There are distinct peaks at approximately 7.5 ppm, 3.5 ppm, and 1.2 ppm. Each peak corresponds to a different type of hydrogen environment in the analyzed compound. #### Multiple Choice Section: - The options below the graph are unlabeled circles with Roman numerals: - ○ I - ○ II - ○ III - ○ IV These options might correspond to possible answers related to the analysis of the NMR spectrum or different compounds potentially being analyzed. This graph serves as a fundamental tool for students and researchers in organic chemistry to infer the structure of molecules based on their hydrogen environments.
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