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- Beakers (a), (b), and (c) are representations of tiny sections (not to scale) of mixtures made from pure benzene and pure water. Select which beaker gives proper representation of the result when the two pure substances are mixed.Hexane (C6H14, density = 0.766 g/cm3), perfluoro-hexane (C6F14, density = 1.669 g/cm3), and water are immiscible liquids; that is, they do not dissolve in one another. You place 10 mL of each in a graduated cylinder, along with pieces of high-density polyethylene (HDPE, density = 0.97 g/cm3), polyvinyl chloride(PVC, density = 1.36 g/cm3), and Teflon (density = 2.3 g/cm3). None of these common plastics dissolves in these liquids. Describe what you expect to see.As part of a science project, you study traffic patterns in your city at an intersection in the middle of downtown. You set up a device that counts the ears passing through this intersection for a 24-hr period during a weekday. The graph of hourly traffic looks like this. a. At what time(s) does the highest number of cars pass through die intersection? b. At what time(s) does the lowest number of cars pass through die intersection? c. Briefly describe the trend in numbers of cars over the course of die day. d. Provide a hypothesis explaining the trend in numbers of cars over the course of the day. e. Provide a possible experiment that could test your hypothesis.
- The mass fraction of gold in seawater is 1 103 ppm. Earths oceans contain 3.5 1020 gal seawater. Estimate how many pounds of gold are in the oceans. 1 gal = 3.785 L; 1 lb = 454 g.Suppose that you are closing a cabin in the north woods for the winter and you do not want the water in the toilet tank to freeze. You know that the temperature might get as low as 30. C, and you want to protect about 4.0 L water in the toilet tank from freezing. Calculate the volume of ethylene glycol (density = 1.113 g/mL; molar mass = 62.1 g/mol) you should add to the 4.0 L water.Which part of the description of a compound or element refers to its physical properties and which to its chemical properties? (a) Calcium carbonate is a white solid with a density of 2.71 g/cm3. It reacts readily with an acid to produce gaseous carbon dioxide. (b) Gray, powdered zinc metal reacts with purple iodine to give a white compound
- Some scientists think there are living things smaller than bacteria (New York Times, January 18, 2000, p. D1). Called nanobes, they are roughly cylindrical and range from 20 to 150 nm long and about 10 nm in diameter. One approach to determining whether nanobes are living is to estimate how many atoms and molecules could make up a nanobe. If the number is too small, then there would not be enough DNA, protein, and other biological molecules to carry out life processes. To test this method, estimate an upper limit for the number of atoms that could be in a nanobe. (Use a small atom, such as hydrogen.) Also estimate how many protein molecules could fit inside a nanobe. Do your estimates rule out the possibility that a nanobe could be living? Explain why or why not.On October 21, 1982, the Bureau of the Mint changed the composition of pennies (see Exercise 120). Instead of an alloy of 95% Cu and 5% Zn by mass, a core of 99.2% Zn and 0.8% Cu with a thin shell of copper was adopted. The overall composition of the new penny was 97.6% Zn and 2.4% Cu by mass. Does this account for the difference in mass among die pennies in Exercise 120? Assume the volume of the individual metals that make up each penny can be added together to give the overall volume of the penny, and assume each penny is the same size. (Density of Cu = 8.96 g/cm3; density of Zn = 7.14 g/cm3).7.The word pour is commonly used in reference to liquids but not to solids or gases. Can you pour a solid or a gas? Why or why not? If either answer is yes, can you give an example?
- Confronted with the box shown in the diagram, you wish to discover something about its internal workings. You have no tools and cannot open the box. You pull on rope B, and it moves rather freely. When you pull on rope A, rope C appears to be pulled slightly into the box. When you pull on rope C, rope A almost disappears into the box. a. Based on these observations, construct a model for the interior mechanism of the box. b. What further experiments could you do to refine your model?You can analyze for a copper compound in water using an instrument called a spectrophotometer. [A spectrophotometer is a scientific instrument that measures the amount of light (of a given wavelength) that is absorbed by the solution] The amount of light absorbed at a given wavelength of light (A) depends directly on the mass of compound per liter of solution. To calibrate the spectrophotometer, you collect the following data: Plot the absorbance (A) against the mass of copper compound per liter (g/L), and find the slope (m) and intercept (b) (assuming that A is y and the amount in solution is x in the equation for a straight line, y = mx + b). What is the mass of copper compound in the solution in g/L and mg/mL when the absorbance is 0.635?In 1993 the Minnesota Department of Health set a health risk limit for n-butanol in groundwater of 700. µg/L. Suppose an analytical chemist receives a sample of groundwater with a measured volume of 18.0 mL. Calculate the maximum mass in milligrams of n-butanol which the chemist could measure in this sample and still certify that the groundwater from which it came met Minnesota Department of Health standards. Be sure your answer has the correct number of significant digits. mg