Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.12E
Related questions
Question
Need the 3 answers I got wrong. The other two options for the second wrong question are sum and ratio
![Your answer is partially correct.
The reaction of N205 with gaseous H20 is a potentially important reaction in the chemistry of acid rain:
N2O5(g) + H2O(g) → 2HNO3(g)
It is possible to monitor the concentration of N205 with time. Describe a set of isolation experiments from which the rate law and rate
constant for this reaction could be determined.
The isolation method requires that one concentration be substantially smaller than all the others, so the experimental reaction
order follows the order with respect to that one reactant. We are told that it is possible to track the concentration of N205, so this
reactant has to be the one with the
low concentration. Do two experiments; in each, [H2O]o >> [N2O5lo, and with
different
values for [H2O]o. Which graphs do you need to plot to determine order with respect to N205? Select all that apply.
1
1
vs. t
[N2O5] [N2O5 lo
1
1
vs. t
[N2O5]
[N2O5 ]o
1
vs. t
[N2O5 lo
1
vs. t
[N2O5]
O [N2O5 ]o
vs. t
[N2O5]
([N2O5 lo
In
vs. t
[N2O5]
The order with respect to H2O can be determined using the
difference
of slope values and H20 concentrations. To calculate the
true rate constant (k), use the relationship between the observed rate
and k, substituting data from either
of the two experiments.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb1ca4019-f596-47d0-9ac7-d83eaf834e41%2F73653156-51e3-4c6f-9311-ce6154c662db%2F76sk5mi_processed.png&w=3840&q=75)
Transcribed Image Text:Your answer is partially correct.
The reaction of N205 with gaseous H20 is a potentially important reaction in the chemistry of acid rain:
N2O5(g) + H2O(g) → 2HNO3(g)
It is possible to monitor the concentration of N205 with time. Describe a set of isolation experiments from which the rate law and rate
constant for this reaction could be determined.
The isolation method requires that one concentration be substantially smaller than all the others, so the experimental reaction
order follows the order with respect to that one reactant. We are told that it is possible to track the concentration of N205, so this
reactant has to be the one with the
low concentration. Do two experiments; in each, [H2O]o >> [N2O5lo, and with
different
values for [H2O]o. Which graphs do you need to plot to determine order with respect to N205? Select all that apply.
1
1
vs. t
[N2O5] [N2O5 lo
1
1
vs. t
[N2O5]
[N2O5 ]o
1
vs. t
[N2O5 lo
1
vs. t
[N2O5]
O [N2O5 ]o
vs. t
[N2O5]
([N2O5 lo
In
vs. t
[N2O5]
The order with respect to H2O can be determined using the
difference
of slope values and H20 concentrations. To calculate the
true rate constant (k), use the relationship between the observed rate
and k, substituting data from either
of the two experiments.
Expert Solution
Step 1
The answer is as follows:
Step by step
Solved in 2 steps with 1 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:
9781285199023
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning