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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Mustard gas, Cl¬CH2CH2¬S¬CH2CH2¬Cl, was used as a poisonous chemical agent
in World War I. Mustard gas is much more toxic than a typical primary alkyl chloride. Its
toxicity stems from its ability to alkylate amino groups on important
rendering the enzymes inactive.
(a) Propose a mechanism to explain why mustard gas is an exceptionally potent alkylating
agent
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- X6-156. Arrange the following substituted anilines in increasing order of reactivity toward acetic anhydride: sllo NH2 ร้อเป็น NH2 NH2 edi NH2 O₂N. (a) (b) ---- (c) (d) bund NO2 CI H3C-N-CH3 Insmiy X 6-157. Suggest a mechanism for the preparation of acetic anhydride from acetic acid and acetyl chloride in the presence pyridine (an amine base).arrow_forwardWhich compound will undergo decarboxylation (-CO2) most easily when heated? (a) CO2H (b) НО-С HO2C CO2H (c) CO2H (d) CO2H CO2H ČO2H CO2Harrow_forwardCompound A on ozonolysis yields the two products shown. What is the structure of compound A? Compound A 1.03 2. (CH3)2S ||| ol H H || IV H Harrow_forward
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