Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question 7.
1- Write Walden's Cycle of Reactions Interconverting.
2- Mention the product of a nucleophilic substitution reaction of (S)-2-
bromohexane with acetate ion, CH3CO2-
Assume that inversion of configuration occurs, and show the chemistry
of both the reactant and product.
3- Draw the mechanism of the SN2 Reaction. Show the correct directions
of the arrows, and all reagents.
4- Draw the mechanism of the SN1 Reaction. Show the correct directions
of the arrows, and all reagents.
5- Draw the mechanism of the E2 Reaction with an Alkyl Halide. Show
the correct directions of the arrows, and all reagents.
6- Draw the mechanism of the E1 Reaction with an Alkyl Halide. Show
the correct directions of the arrows, and all reagents.
7- Mention the product formed in an SÃ2 reaction between 1-
bromobutane and Nal.
8- Rank the following compounds in order of their expected reactivity
toward SN2 reaction: CH3Br, CH3OT0s, (CH3)2CHCI.
9- Explain Grignard Reagents in details with one example.
10-
Mention how a halogen substituent can be replaced by a
deuterium atom in the preparation of a deuterated compound.
Br
D
|
CH3CHCH₂CH3
?
CH3CHCH₂CH3
expand button
Transcribed Image Text:1- Write Walden's Cycle of Reactions Interconverting. 2- Mention the product of a nucleophilic substitution reaction of (S)-2- bromohexane with acetate ion, CH3CO2- Assume that inversion of configuration occurs, and show the chemistry of both the reactant and product. 3- Draw the mechanism of the SN2 Reaction. Show the correct directions of the arrows, and all reagents. 4- Draw the mechanism of the SN1 Reaction. Show the correct directions of the arrows, and all reagents. 5- Draw the mechanism of the E2 Reaction with an Alkyl Halide. Show the correct directions of the arrows, and all reagents. 6- Draw the mechanism of the E1 Reaction with an Alkyl Halide. Show the correct directions of the arrows, and all reagents. 7- Mention the product formed in an SÃ2 reaction between 1- bromobutane and Nal. 8- Rank the following compounds in order of their expected reactivity toward SN2 reaction: CH3Br, CH3OT0s, (CH3)2CHCI. 9- Explain Grignard Reagents in details with one example. 10- Mention how a halogen substituent can be replaced by a deuterium atom in the preparation of a deuterated compound. Br D | CH3CHCH₂CH3 ? CH3CHCH₂CH3
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