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Make an electron-flow-mechanism for this synthetic scheme. This involves predicting major and by-products using electronic and structural effects. The arrow push mechanism must be shows. (D-GLUCOSE -> ASCORBIC ACID)

Make an electron-flow-mechanism for this synthetic scheme. This involves predicting major and by-products using electronic and structural effects. The arrow push mechanism must be shows. (D-GLUCOSE -> ASCORBIC ACID)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Make an electron-flow-mechanism for this synthetic scheme. This involves predicting major and by-products using electronic and structural effects. The arrow push mechanism must be shows. (D-GLUCOSE -> ASCORBIC ACID)

Мe Me Acetobacter ОН OH ОН OH OH suboxydans рH 4-6, 30-35°C HO 3. Acetone, HO H2SO4 37 % H2 RaNi Me Но Но но OH quant. >90 % OH ОН ОН ОН OH OH Me D-glucose (10) 11 12 13 OH НО 4.NaOCI, NICI, > 93 % 5. H20, H*, 82 % HO 6. HCI, PhMe, A step 3+4 can be replaced by oxidation with Air & НО OH > 60 % HO. 14 OH Ascorbic acid (15) PtO
Transcribed Image Text:Мe Me Acetobacter ОН OH ОН OH OH suboxydans рH 4-6, 30-35°C HO 3. Acetone, HO H2SO4 37 % H2 RaNi Me Но Но но OH quant. >90 % OH ОН ОН ОН OH OH Me D-glucose (10) 11 12 13 OH НО 4.NaOCI, NICI, > 93 % 5. H20, H*, 82 % HO 6. HCI, PhMe, A step 3+4 can be replaced by oxidation with Air & НО OH > 60 % HO. 14 OH Ascorbic acid (15) PtO
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