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- en to 25) What get of reagents wood produce Hhe prod. shown in the highest yield? 7? H. STOM el anoitoesy oniwolict er to roiriW lo rioDraw tructural or or he ajor roduct f he eaction shown. CH3CH=CHCH3 Cl2 • Do not show stereóchemist in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. • Show product stereochem IF the reactant alkene has both carbons of the double bond within a ring. C. opy P. C. progress ChemDoodle (Previous Submit Answer Retry Entire Group 9 more group attempts remainingcan you help with quesiton 12
- B. Draw the product of vinylcyclohexane with H₂SO4 and H₂O. OH IncorrectFor esch of the following two reactions draw the major product. Br,, hv KMNO, heat7. Piirrä seuraavan reaktion mekanismi. Vinkki: Mekanismiin sisältyy karbokationin toisiintuminen ja myös sek. karbokationivälivaihe. / Draw the mechanism for following reaction. Hint: The mechanism includes carbocation rearrangement and also a secondary carbocation intermediate. do CI CH3OH
- 24. Which product is formed by the reaction ? A) | B) || C) ||| D) IV Br ОН NaH Br ... هستم IV4) Give the correct product with the correct stereochemistry. Me Me 5) Give the major product. hv HCI OC5. Draw the major product of the following reactions. Classify each reaction as substitution, elimination, or addition. Indicate if there are any rearrangement products. If the reaction does not proceed, explain why. H₂O, H* HO OH 1) Hg(OAc)2 2) NaBH4 H3PO4 H₂SO4, 100 °C 1) BH3*THF 2) HOOH, -OH CI NaN3 (1 equiv) THF
- V. @Given the following reaction show the detailed mechanism fer me 1 Conversion of A tu B •OCN3 OYOCH'S (A) Na och 3 CH3OH. almost the Ⓒ detailed using the identical. cyclonexare ving as a structure and .d. cyclopentane ning instead (B) OH а mechanism, instead of shoaln in product B, propase mechanism fer a product W/ a cyclohexane ving.Draw tructu f he ajor rganic roduct f he ollowing reaction. CH2 1. Hg(OAc)2, H20 2. NaBH4 CH3 • In cases where there is more than one answer, just draw one. •You do not have to consider stereochemistry. [ドPlastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside the lenses that occurs when the lenses are exposed to sunlight. The original dye absorbs UV light but not visible light and is thus colorless, while the rearrangement product absorbs visible light and is thus darkened. (a) Show the mechanism of the rearrangement. (b) Why does the rearrangement product absorb at a longer wavelength (visible light) than the original dye (UV)?
