Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Macmillan Learning
Use the table of bond dissociation energies to calculate and compare the enthalpy of monobromination and monochlorination
for the given alkyl position.
Bond Dissociation Energies (for A-B- A+B)
Bond broken
H-H
Br-Br
CI-CI
CH₂CH₂CH₂-H+ Br₂
CH₂CH₂CH₂-H + Cl₂
AH (kJ/mol) Bond broken AH (kJ/mol)
436
366
193
432
243
H-Br
H-Cl
CH₂CH₂CH₂-Br + HBr
CH₂CH₂CH₂-CI+HCI
Bond broken AH (kJ/mol)
CH₂CH₂CH₂-H
423
CH₂CH₂CH₂-Br
294
CH₂CH₂CH₂-CI
354
AH =
ΔΗ =
-58
Incorrect
-131
Incorrect
kJ/mol
kJ/mol
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Transcribed Image Text:Macmillan Learning Use the table of bond dissociation energies to calculate and compare the enthalpy of monobromination and monochlorination for the given alkyl position. Bond Dissociation Energies (for A-B- A+B) Bond broken H-H Br-Br CI-CI CH₂CH₂CH₂-H+ Br₂ CH₂CH₂CH₂-H + Cl₂ AH (kJ/mol) Bond broken AH (kJ/mol) 436 366 193 432 243 H-Br H-Cl CH₂CH₂CH₂-Br + HBr CH₂CH₂CH₂-CI+HCI Bond broken AH (kJ/mol) CH₂CH₂CH₂-H 423 CH₂CH₂CH₂-Br 294 CH₂CH₂CH₂-CI 354 AH = ΔΗ = -58 Incorrect -131 Incorrect kJ/mol kJ/mol
Construct a three-step synthesis of 1-bromopropane from propane by dragging the appropriate formulas into the bins. Note that
each bin will hold only one item, and not all of the given reagents or structures will be used.
Reactant
(propane)
(CH₂)₂CHBr
CH,CH(Br)CH,B
Reagent
CH₂CH₂CH₂Br
Br₂, hu
Step 1 Product
HBF, ROOR
NBS, ROOR
Reagent2
Answer Bank
(CH,)CO K+
CH₂CH=CH₂
Step 2 Product
Br₂
CH,CH=CHBr
Reagent3
HBr
Final Product
(1-bromopropane)
CH, CH₂CH,
..
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Transcribed Image Text:Construct a three-step synthesis of 1-bromopropane from propane by dragging the appropriate formulas into the bins. Note that each bin will hold only one item, and not all of the given reagents or structures will be used. Reactant (propane) (CH₂)₂CHBr CH,CH(Br)CH,B Reagent CH₂CH₂CH₂Br Br₂, hu Step 1 Product HBF, ROOR NBS, ROOR Reagent2 Answer Bank (CH,)CO K+ CH₂CH=CH₂ Step 2 Product Br₂ CH,CH=CHBr Reagent3 HBr Final Product (1-bromopropane) CH, CH₂CH, ..
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