Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as follows: 2A + В - 2C (all gases) The method of initial rates is used to determine the rate law for this reaction. JA], initial 0.0100 M 0.0200 M 0.0100 M |B], initial 0.0400 M 0.0200 M 0.0200 M Rate (M/sec) 7.5 x 10* 3.0 x 10² 7.5 x 10* Experiment 2 3 The following four mechanisms can be considered along with the data given above. a) A + D + C ½B + D → C fast equilibrium slow b) А + A + В - D с + с slow fast D c) A + A + D ½B D + D fast equilibrium slow C + D d) A + A B + D + C slow fast equilibrium

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Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as
follows:
2A + В - 2C
(all gases)
The method of initial rates is used to determine the rate law for this reaction.
JA], initial
0.0100 M
0.0200 M
0.0100 M
|B], initial
0.0400 M
0.0200 M
0.0200 M
Rate (M/sec)
7.5 x 10*
3.0 x 10²
7.5 x 10*
Experiment
2
3
The following four mechanisms can be considered along with the data given above.
a) A + D + C
½B + D → C
fast equilibrium
slow
b) А + A + В - D
с + с
slow
fast
D
c) A + A
+ D
½B
D + D
fast equilibrium
slow
C + D
d) A + A
B + D + C
slow
fast equilibrium
Transcribed Image Text:Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as follows: 2A + В - 2C (all gases) The method of initial rates is used to determine the rate law for this reaction. JA], initial 0.0100 M 0.0200 M 0.0100 M |B], initial 0.0400 M 0.0200 M 0.0200 M Rate (M/sec) 7.5 x 10* 3.0 x 10² 7.5 x 10* Experiment 2 3 The following four mechanisms can be considered along with the data given above. a) A + D + C ½B + D → C fast equilibrium slow b) А + A + В - D с + с slow fast D c) A + A + D ½B D + D fast equilibrium slow C + D d) A + A B + D + C slow fast equilibrium
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