It is tempting to maximize the amount of product isolated by continuing the fractional distillation until no solution remains in the distilling flask.  Why is this not done?

Macroscale and Microscale Organic Experiments
7th Edition
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Kenneth L. Williamson, Katherine M. Masters
Chapter5: Distillation
Section: Chapter Questions
Problem 7Q: In fractional distillation, liquid can be seen running from the bottom of the distillation column...
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It is tempting to maximize the amount of product isolated by continuing the fractional distillation until no solution remains in the distilling flask.  Why is this not done?

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