Iron(II) forms a complex in hemoglobin. Two of the possibilities are [Fe(H2O)6]2+ and [Fe(CN)6]4–(a) [Fe(H2O)6]2+ and [Fe(CN)6]4– should have the same geometry. What is this coordination environment? Draw it please.(b) For both [Fe(H2O)6]2+ and [Fe(CN)6]4–, draw an energy diagram showing orbital splitting(c) Predict the number of unpaired electrons(d) Identify the ion as low spin or high spin.(e) Is either ion paramagnetic?(f) What would the color of each form of these forms ofhemoglobin?

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Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Iron(II) forms a complex in hemoglobin. Two of the possibilities are [Fe(H₂O)₆]²⁺ and [Fe(CN)₆]^4–

(a) [Fe(H₂O)6]²⁺ and [Fe(CN)₆]^4– should have the same geometry. What is this coordination environment? Draw it please.

(b) For both [Fe(H₂O)₆]²⁺ and [Fe(CN)₆]^4–, draw an energy diagram showing orbital splitting

(c) Predict the number of unpaired electrons
(d) Identify the ion as low spin or high spin.
(e) Is either ion paramagnetic?
(f) What would the color of each form of these forms of
hemoglobin?

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