(a) Consider the following two Fe complex ions: Complex A - [Fe(H2O)3(OH)3] and Complex B [Fe(CO)6]2+ (i) Draw the d-electron configuration for A and B. Label each set of orbitals. (ii) Explain how the d-electron configuration changes when iron is replaced by osmium in A and B. (iii) Calculate the CFSE for A and B. Show all calculations and units. (iv) Which of these two complexes (A or B) will interact with a magnet? Motivate your answer.
(a) Consider the following two Fe complex ions: Complex A - [Fe(H2O)3(OH)3] and Complex B [Fe(CO)6]2+ (i) Draw the d-electron configuration for A and B. Label each set of orbitals. (ii) Explain how the d-electron configuration changes when iron is replaced by osmium in A and B. (iii) Calculate the CFSE for A and B. Show all calculations and units. (iv) Which of these two complexes (A or B) will interact with a magnet? Motivate your answer.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(a) Consider the following two Fe complex ions:
Complex A - [Fe(H2O)3(OH)3] and Complex B [Fe(CO)6]2+
(i) Draw the d-electron configuration for A and B. Label each set of orbitals.
(ii) Explain how the d-electron configuration changes when iron is replaced by
osmium in A and B.
(iii) Calculate the CFSE for A and B. Show all calculations and units.
(iv) Which of these two complexes (A or B) will interact with a magnet? Motivate
your answer.
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