(a) Consider the following two Fe complex ions: Complex A - [Fe(H2O)3(OH)3]  and  Complex B [Fe(CO)6]2+ (i) Draw the d-electron configuration for A and B. Label each set of orbitals. (ii) Explain how the d-electron configuration changes when iron is replaced by osmium in A and B. (iii) Calculate the CFSE for A and B. Show all calculations and units. (iv) Which of these two complexes (A or B) will interact with a magnet? Motivate your answer.

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(a) Consider the following two Fe complex ions:
Complex A - [Fe(H2O)3(OH)3]  and  Complex B [Fe(CO)6]2+

(i) Draw the d-electron configuration for A and B. Label each set of orbitals.
(ii) Explain how the d-electron configuration changes when iron is replaced by
osmium in A and B.
(iii) Calculate the CFSE for A and B. Show all calculations and units.
(iv) Which of these two complexes (A or B) will interact with a magnet? Motivate
your answer.

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